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Study on the Adsorption Properties of Oxalic Acid-Modified Cordierite Honeycomb Ceramics for Neutral Red Dyes

[Image: see text] Removal of organic dyes from water by monolithic adsorbents is considered as an efficient and no-secondary pollution method. Herein, for the first time cordierite honeycomb ceramics (COR) treated with oxalic acid (CORA) were synthesized. This CORA exhibits outstanding removal effic...

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Autores principales: Yang, Shuhui, Cheng, Qingyan, Hu, Liangyan, Gu, Yunhan, Wang, Yanji, Liu, Zhenfa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10061635/
https://www.ncbi.nlm.nih.gov/pubmed/37008113
http://dx.doi.org/10.1021/acsomega.3c00305
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author Yang, Shuhui
Cheng, Qingyan
Hu, Liangyan
Gu, Yunhan
Wang, Yanji
Liu, Zhenfa
author_facet Yang, Shuhui
Cheng, Qingyan
Hu, Liangyan
Gu, Yunhan
Wang, Yanji
Liu, Zhenfa
author_sort Yang, Shuhui
collection PubMed
description [Image: see text] Removal of organic dyes from water by monolithic adsorbents is considered as an efficient and no-secondary pollution method. Herein, for the first time cordierite honeycomb ceramics (COR) treated with oxalic acid (CORA) were synthesized. This CORA exhibits outstanding removal efficiency toward the azo neutral red dyes (NR) from water. After optimizing the reaction conditions, the highest adsorption capacity of 7.35 mg·g(–1) and a removal rate of 98.89% could be achieved within 300 min. Furthermore, investigation of the adsorption kinetics indicated this adsorption process could be described as a pseudo-second-order kinetic model with k(2) and q(e) of 0.0114 g·mg(–1)·min(–1) and 6.94 mg·g(–1), respectively. According to the fitting calculation, the adsorption isotherm could also be described as the Freundlich isotherm model. The removal efficiency could be maintained above 50% after 4 cycles, negating the need for toxic organic solvent extraction, offering a method for bringing the technology one step closer to industrial application and giving CORA promising potential in practical water treatment.
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spelling pubmed-100616352023-03-31 Study on the Adsorption Properties of Oxalic Acid-Modified Cordierite Honeycomb Ceramics for Neutral Red Dyes Yang, Shuhui Cheng, Qingyan Hu, Liangyan Gu, Yunhan Wang, Yanji Liu, Zhenfa ACS Omega [Image: see text] Removal of organic dyes from water by monolithic adsorbents is considered as an efficient and no-secondary pollution method. Herein, for the first time cordierite honeycomb ceramics (COR) treated with oxalic acid (CORA) were synthesized. This CORA exhibits outstanding removal efficiency toward the azo neutral red dyes (NR) from water. After optimizing the reaction conditions, the highest adsorption capacity of 7.35 mg·g(–1) and a removal rate of 98.89% could be achieved within 300 min. Furthermore, investigation of the adsorption kinetics indicated this adsorption process could be described as a pseudo-second-order kinetic model with k(2) and q(e) of 0.0114 g·mg(–1)·min(–1) and 6.94 mg·g(–1), respectively. According to the fitting calculation, the adsorption isotherm could also be described as the Freundlich isotherm model. The removal efficiency could be maintained above 50% after 4 cycles, negating the need for toxic organic solvent extraction, offering a method for bringing the technology one step closer to industrial application and giving CORA promising potential in practical water treatment. American Chemical Society 2023-03-20 /pmc/articles/PMC10061635/ /pubmed/37008113 http://dx.doi.org/10.1021/acsomega.3c00305 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Yang, Shuhui
Cheng, Qingyan
Hu, Liangyan
Gu, Yunhan
Wang, Yanji
Liu, Zhenfa
Study on the Adsorption Properties of Oxalic Acid-Modified Cordierite Honeycomb Ceramics for Neutral Red Dyes
title Study on the Adsorption Properties of Oxalic Acid-Modified Cordierite Honeycomb Ceramics for Neutral Red Dyes
title_full Study on the Adsorption Properties of Oxalic Acid-Modified Cordierite Honeycomb Ceramics for Neutral Red Dyes
title_fullStr Study on the Adsorption Properties of Oxalic Acid-Modified Cordierite Honeycomb Ceramics for Neutral Red Dyes
title_full_unstemmed Study on the Adsorption Properties of Oxalic Acid-Modified Cordierite Honeycomb Ceramics for Neutral Red Dyes
title_short Study on the Adsorption Properties of Oxalic Acid-Modified Cordierite Honeycomb Ceramics for Neutral Red Dyes
title_sort study on the adsorption properties of oxalic acid-modified cordierite honeycomb ceramics for neutral red dyes
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10061635/
https://www.ncbi.nlm.nih.gov/pubmed/37008113
http://dx.doi.org/10.1021/acsomega.3c00305
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