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Deep multilevel wet etching of fused silica glass microstructures in BOE solution

Fused silica glass is a material of choice for micromechanical, microfluidic, and optical devices due to its chemical resistance, optical, electrical, and mechanical performance. Wet etching is the key method for fabricating of such microdevices. Protective mask integrity is a big challenge due extr...

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Autores principales: Konstantinova, T. G., Andronic, M. M., Baklykov, D. A., Stukalova, V. E., Ezenkova, D. A., Zikiy, E. V., Bashinova, M. V., Solovev, A. A., Lotkov, E. S., Ryzhikov, I. A., Rodionov, I. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10063648/
https://www.ncbi.nlm.nih.gov/pubmed/36997654
http://dx.doi.org/10.1038/s41598-023-32503-w
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author Konstantinova, T. G.
Andronic, M. M.
Baklykov, D. A.
Stukalova, V. E.
Ezenkova, D. A.
Zikiy, E. V.
Bashinova, M. V.
Solovev, A. A.
Lotkov, E. S.
Ryzhikov, I. A.
Rodionov, I. A.
author_facet Konstantinova, T. G.
Andronic, M. M.
Baklykov, D. A.
Stukalova, V. E.
Ezenkova, D. A.
Zikiy, E. V.
Bashinova, M. V.
Solovev, A. A.
Lotkov, E. S.
Ryzhikov, I. A.
Rodionov, I. A.
author_sort Konstantinova, T. G.
collection PubMed
description Fused silica glass is a material of choice for micromechanical, microfluidic, and optical devices due to its chemical resistance, optical, electrical, and mechanical performance. Wet etching is the key method for fabricating of such microdevices. Protective mask integrity is a big challenge due extremely aggressive properties of etching solution. Here, we propose multilevel microstructures fabrication route based on fused silica deep etching through a stepped mask. First, we provide an analysis of a fused silica dissolution mechanism in buffered oxide etching (BOE) solution and calculate the main fluoride fractions like [Formula: see text] , [Formula: see text] , [Formula: see text] as a function of pH and NH(4)F:HF ratio. Then, we experimentally investigate the influence of BOE composition (1:1–14:1) on the mask resistance, etch rate and profile isotropy during deep etching through a metal/photoresist mask. Finally, we demonstrate a high-quality multilevel over-200 μm etching process with the rate up to 3 μm/min, which could be of a great interest for advanced microdevices with flexure suspensions, inertial masses, microchannels, and through-wafer holes.
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spelling pubmed-100636482023-04-01 Deep multilevel wet etching of fused silica glass microstructures in BOE solution Konstantinova, T. G. Andronic, M. M. Baklykov, D. A. Stukalova, V. E. Ezenkova, D. A. Zikiy, E. V. Bashinova, M. V. Solovev, A. A. Lotkov, E. S. Ryzhikov, I. A. Rodionov, I. A. Sci Rep Article Fused silica glass is a material of choice for micromechanical, microfluidic, and optical devices due to its chemical resistance, optical, electrical, and mechanical performance. Wet etching is the key method for fabricating of such microdevices. Protective mask integrity is a big challenge due extremely aggressive properties of etching solution. Here, we propose multilevel microstructures fabrication route based on fused silica deep etching through a stepped mask. First, we provide an analysis of a fused silica dissolution mechanism in buffered oxide etching (BOE) solution and calculate the main fluoride fractions like [Formula: see text] , [Formula: see text] , [Formula: see text] as a function of pH and NH(4)F:HF ratio. Then, we experimentally investigate the influence of BOE composition (1:1–14:1) on the mask resistance, etch rate and profile isotropy during deep etching through a metal/photoresist mask. Finally, we demonstrate a high-quality multilevel over-200 μm etching process with the rate up to 3 μm/min, which could be of a great interest for advanced microdevices with flexure suspensions, inertial masses, microchannels, and through-wafer holes. Nature Publishing Group UK 2023-03-30 /pmc/articles/PMC10063648/ /pubmed/36997654 http://dx.doi.org/10.1038/s41598-023-32503-w Text en © The Author(s) 2023 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Article
Konstantinova, T. G.
Andronic, M. M.
Baklykov, D. A.
Stukalova, V. E.
Ezenkova, D. A.
Zikiy, E. V.
Bashinova, M. V.
Solovev, A. A.
Lotkov, E. S.
Ryzhikov, I. A.
Rodionov, I. A.
Deep multilevel wet etching of fused silica glass microstructures in BOE solution
title Deep multilevel wet etching of fused silica glass microstructures in BOE solution
title_full Deep multilevel wet etching of fused silica glass microstructures in BOE solution
title_fullStr Deep multilevel wet etching of fused silica glass microstructures in BOE solution
title_full_unstemmed Deep multilevel wet etching of fused silica glass microstructures in BOE solution
title_short Deep multilevel wet etching of fused silica glass microstructures in BOE solution
title_sort deep multilevel wet etching of fused silica glass microstructures in boe solution
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10063648/
https://www.ncbi.nlm.nih.gov/pubmed/36997654
http://dx.doi.org/10.1038/s41598-023-32503-w
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