Phosphanyl-substituted tin half-sandwich complexes

Phosphanyl-substituted tin(ii) half sandwich complexes are reported. Due to the Lewis acidic tin center and Lewis basic phosphorous atom they form head-to-tail dimers. Their properties and reactivities were investigated both experimentally and theoretically. Furthermore, related transition metal com...

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Detalles Bibliográficos
Autores principales: Müller, Carsten, Schu, Justin, Morgenstern, Bernd, Zimmer, Michael, Schmidtmann, Marc, Schäfer, André
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10065063/
https://www.ncbi.nlm.nih.gov/pubmed/37006362
http://dx.doi.org/10.1039/d3ra01384g
Descripción
Sumario:Phosphanyl-substituted tin(ii) half sandwich complexes are reported. Due to the Lewis acidic tin center and Lewis basic phosphorous atom they form head-to-tail dimers. Their properties and reactivities were investigated both experimentally and theoretically. Furthermore, related transition metal complexes of these species are presented.

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