Phosphanyl-substituted tin half-sandwich complexes

Phosphanyl-substituted tin(ii) half sandwich complexes are reported. Due to the Lewis acidic tin center and Lewis basic phosphorous atom they form head-to-tail dimers. Their properties and reactivities were investigated both experimentally and theoretically. Furthermore, related transition metal com...

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Detalles Bibliográficos
Autores principales: Müller, Carsten, Schu, Justin, Morgenstern, Bernd, Zimmer, Michael, Schmidtmann, Marc, Schäfer, André
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10065063/
https://www.ncbi.nlm.nih.gov/pubmed/37006362
http://dx.doi.org/10.1039/d3ra01384g
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author Müller, Carsten
Schu, Justin
Morgenstern, Bernd
Zimmer, Michael
Schmidtmann, Marc
Schäfer, André
author_facet Müller, Carsten
Schu, Justin
Morgenstern, Bernd
Zimmer, Michael
Schmidtmann, Marc
Schäfer, André
author_sort Müller, Carsten
collection PubMed
description Phosphanyl-substituted tin(ii) half sandwich complexes are reported. Due to the Lewis acidic tin center and Lewis basic phosphorous atom they form head-to-tail dimers. Their properties and reactivities were investigated both experimentally and theoretically. Furthermore, related transition metal complexes of these species are presented.
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spelling pubmed-100650632023-04-01 Phosphanyl-substituted tin half-sandwich complexes Müller, Carsten Schu, Justin Morgenstern, Bernd Zimmer, Michael Schmidtmann, Marc Schäfer, André RSC Adv Chemistry Phosphanyl-substituted tin(ii) half sandwich complexes are reported. Due to the Lewis acidic tin center and Lewis basic phosphorous atom they form head-to-tail dimers. Their properties and reactivities were investigated both experimentally and theoretically. Furthermore, related transition metal complexes of these species are presented. The Royal Society of Chemistry 2023-03-31 /pmc/articles/PMC10065063/ /pubmed/37006362 http://dx.doi.org/10.1039/d3ra01384g Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Müller, Carsten
Schu, Justin
Morgenstern, Bernd
Zimmer, Michael
Schmidtmann, Marc
Schäfer, André
Phosphanyl-substituted tin half-sandwich complexes
title Phosphanyl-substituted tin half-sandwich complexes
title_full Phosphanyl-substituted tin half-sandwich complexes
title_fullStr Phosphanyl-substituted tin half-sandwich complexes
title_full_unstemmed Phosphanyl-substituted tin half-sandwich complexes
title_short Phosphanyl-substituted tin half-sandwich complexes
title_sort phosphanyl-substituted tin half-sandwich complexes
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10065063/
https://www.ncbi.nlm.nih.gov/pubmed/37006362
http://dx.doi.org/10.1039/d3ra01384g
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AT zimmermichael phosphanylsubstitutedtinhalfsandwichcomplexes
AT schmidtmannmarc phosphanylsubstitutedtinhalfsandwichcomplexes
AT schaferandre phosphanylsubstitutedtinhalfsandwichcomplexes

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