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3-sulfonyloxyaryl(mesityl)iodonium triflates as 1,2-benzdiyne precursors with activation via ortho-deprotonative elimination strategy

Benzyne has long captivated the attention of chemists and has gained numerous synthetic achievements. Among typical benzyne generation methods, removal of two vicinal substituents from 1,2-difunctionalized benzenes, i.e., Kobayashi’s protocol, are prevailing, while ortho-deprotonative elimination fr...

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Detalles Bibliográficos
Autores principales: Yuan, Haoyin, Yin, Wenhao, Hu, Jili, Li, Yang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10070408/
https://www.ncbi.nlm.nih.gov/pubmed/37012251
http://dx.doi.org/10.1038/s41467-023-37196-3

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