Mn(I)-catalyzed sigmatropic rearrangement of β, γ-unsaturated alcohols

Sigmatropic rearrangement provides a versatile strategy to site-selectively reorganize carbon-skeleton with high atom- and step-economy. Herein, we disclose a Mn(I)-catalyzed sigmatropic rearrangement of β, γ-unsaturated alcohols via C-C σ bond activation. A variety of α-aryl-allylic alcohols and α-...

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Detalles Bibliográficos
Autores principales: Yang, Can, Zhou, Xiaoyu, Shen, Lixing, Ke, Zhuofeng, Jiang, Huanfeng, Zeng, Wei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10070501/
https://www.ncbi.nlm.nih.gov/pubmed/37012237
http://dx.doi.org/10.1038/s41467-023-37299-x

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10070501/
https://www.ncbi.nlm.nih.gov/pubmed/37012237
http://dx.doi.org/10.1038/s41467-023-37299-x

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