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Mn(I)-catalyzed sigmatropic rearrangement of β, γ-unsaturated alcohols

Sigmatropic rearrangement provides a versatile strategy to site-selectively reorganize carbon-skeleton with high atom- and step-economy. Herein, we disclose a Mn(I)-catalyzed sigmatropic rearrangement of β, γ-unsaturated alcohols via C-C σ bond activation. A variety of α-aryl-allylic alcohols and α-...

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Detalles Bibliográficos
Autores principales:	Yang, Can, Zhou, Xiaoyu, Shen, Lixing, Ke, Zhuofeng, Jiang, Huanfeng, Zeng, Wei
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2023
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10070501/ https://www.ncbi.nlm.nih.gov/pubmed/37012237 http://dx.doi.org/10.1038/s41467-023-37299-x

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