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Probing the donor strength of yldiide ligands: synthesis, structure and reactivity of rhodium complexes with a PC(ylide)N pincer ligand

Control of the metal ligand interaction by changes in the ligand protonation state is vital to many catalytic transformations based on metal–ligand cooperativity. Herein, we report on the coordination chemistry of a new PC(y)(H)N pincer ligand with a central ylide as donor site, which through deprot...

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Detalles Bibliográficos
Autores principales: Lapointe, Sébastien, Duari, Prakash, Gessner, Viktoria H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10074424/
https://www.ncbi.nlm.nih.gov/pubmed/37035690
http://dx.doi.org/10.1039/d2sc06759e