Admirable stability achieved by ns(2) ions Co-doping for all-inorganic metal halides towards optical anti-counterfeiting

Optical materials play a momentous role in anti-counterfeiting field, such as authentication, currency and security. The development of tunable optical properties and optical responses to a range of external stimuli is quite imperative for the growing demand of optical anti-counterfeiting technology. Metal halide perovskites have attracted much attention of researchers due to their excellent optical properties. In addition, co-doping methods have been gradually applied to the research of metal halide perovskites, by which more abundant luminescence phenomena can be introduced into the host perovskite. Herein, the ns(2) ions of bismuth (Bi(3+)) and antimony (Sb(3+)) ions co-doped zero-dimensional Cs(2)SnCl(6) metal halide with an excitation-wavelength-dependent emission phenomenon is synthesized as an efficient multimodal luminescent material, the luminescence of which is tunable and covers a wide region of color. What's more, a dynamic dual-emission phenomenon is captured when the excitation wavelength changes from 320 nm to 420 nm for Cs(2)SnCl(6):Bi(0.08)Sb(0.12) crystals. Moreover, the Bi(3+) and Sb(3+) doped metal halide material shows great enhancement in solvent resistance and thermal stability compared to the pristine Cs(2)SnCl(6). The admirable stability and distinguishable photoluminescence (PL) phenomenon of this all-inorganic metal halide has great potential to be applied in optical anti-counterfeiting technology. Furthermore, the co-doping method can accelerate the discovery of new luminescence phenomena in original metal halide perovskites.