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UiO66-Derived Catalyst for Low Temperature Catalytic Reduction of NO with NH(3)

[Image: see text] Diesel exhaust emissions are major outdoor air pollutants. Reducing the emission of NOx by diesel commercial vehicles and related machineries is at present a great challenge. In this study, we synthesize a catalyst for low-temperature catalytic reduction of NO using calcinated UiO-...

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Detalles Bibliográficos
Autores principales: Leung, Ka-Ming, Tsui, Chi-Kin J., Ho, Ching-Kit, Liao, Chang-Zhong, Yau, Hei-Tung, Chan, Kwong-Yu, Li, Chi-Ying V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10077550/
https://www.ncbi.nlm.nih.gov/pubmed/37033813
http://dx.doi.org/10.1021/acsomega.2c07110
Descripción
Sumario:[Image: see text] Diesel exhaust emissions are major outdoor air pollutants. Reducing the emission of NOx by diesel commercial vehicles and related machineries is at present a great challenge. In this study, we synthesize a catalyst for low-temperature catalytic reduction of NO using calcinated UiO-66(Zr) as a host for the doping of cerium, manganese, and titanium by the incipient wetness impregnation, followed by the dispersion of 1.0 wt % platinum. A solid solution of Ce(0.15)Zr(0.54)Mn(0.11)Ti(0.20)O(2)/1.0Pt (CZMTO/Pt) is synthesized as evident by the structural characterizations. The catalyst demonstrates significant NO reduction in the laboratory due to the synergistic effect of various elements, with NO conversion above 80% at 160 °C.