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One-Step Fabrication of the ZnO/g-C(3)N(4) Composite for Visible Light-Responsive Photocatalytic Degradation of Bisphenol E in Aqueous Solution
[Image: see text] The ZnO/g-C(3)N(4) composite was successfully synthesized by a simple one-step calcination of a urea and zinc acetate mixture. The photocatalytic activity of the synthesized composite was evaluated in the degradation of bisphenol E (BPE). The morphology, crystallinity, optical prop...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10077555/ https://www.ncbi.nlm.nih.gov/pubmed/37033806 http://dx.doi.org/10.1021/acsomega.2c06678 |
Sumario: | [Image: see text] The ZnO/g-C(3)N(4) composite was successfully synthesized by a simple one-step calcination of a urea and zinc acetate mixture. The photocatalytic activity of the synthesized composite was evaluated in the degradation of bisphenol E (BPE). The morphology, crystallinity, optical properties, and composition of the synthesized composite were characterized by using various analytical techniques such as scanning electron microscopy (SEM), transmitted electron microscopy (TEM), field emission-electron probe microanalysis (FE-EPMA), nitrogen adsorption and desorption isotherm measurement, Fourier-transform infrared (FTIR) spectroscopy, X-ray powder diffraction (XRD), diffuse reflectance spectroscopy (DRS), photoluminescence (PL) spectroscopy, electrochemical impedance spectroscopy (EIS), X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis (TGA). The degradation rate of BPE with the ZnO/g-C(3)N(4) composite was 8 times larger than that obtained with pure g-C(3)N(4) at the optimal conditions. The excellent photocatalytic activity was attributed to the synergistic effect between the g-C(3)N(4) and ZnO, which enhanced the efficiency of charge separations, reduced the e(–)/h(+) pairs recombination, and increased the visible light absorption ability. The radical scavenger studies indicated that the (•)O(2)(–) and h(+) species were mainly responsible for the degradation of BPE. The stability test suggested the chemical and photostability of the synthesized composite. Two possible photocatalytical mechanisms have been suggested. |
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