Access to germasiloxanes and alkynylgermanes mediated by earth-abundant species

The reactions between silanols or terminal acetylenes with alkynylgermanes have been accomplished using potassium bis(trimethylsilyl)amide as the catalyst. This strategy has provided an entry point into various organogermanes including germasiloxanes and alkynylgermanes. Remarkably, not only KHMDS b...

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Detalles Bibliográficos
Autores principales: Stachowiak-Dłużyńska, Hanna, Kuciński, Krzysztof, Broniarz, Konstancja, Szafoni, Ewelina, Gruszczyński, Marcin, Lewandowski, Dariusz, Consiglio, Giuseppe, Hreczycho, Grzegorz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10079689/
https://www.ncbi.nlm.nih.gov/pubmed/37024548
http://dx.doi.org/10.1038/s41598-023-32172-9
Descripción
Sumario:The reactions between silanols or terminal acetylenes with alkynylgermanes have been accomplished using potassium bis(trimethylsilyl)amide as the catalyst. This strategy has provided an entry point into various organogermanes including germasiloxanes and alkynylgermanes. Remarkably, not only KHMDS but also simple bases such as KOH can serve as efficient catalysts in this process.

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