Access to germasiloxanes and alkynylgermanes mediated by earth-abundant species

The reactions between silanols or terminal acetylenes with alkynylgermanes have been accomplished using potassium bis(trimethylsilyl)amide as the catalyst. This strategy has provided an entry point into various organogermanes including germasiloxanes and alkynylgermanes. Remarkably, not only KHMDS b...

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Autores principales: Stachowiak-Dłużyńska, Hanna, Kuciński, Krzysztof, Broniarz, Konstancja, Szafoni, Ewelina, Gruszczyński, Marcin, Lewandowski, Dariusz, Consiglio, Giuseppe, Hreczycho, Grzegorz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10079689/
https://www.ncbi.nlm.nih.gov/pubmed/37024548
http://dx.doi.org/10.1038/s41598-023-32172-9
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author Stachowiak-Dłużyńska, Hanna
Kuciński, Krzysztof
Broniarz, Konstancja
Szafoni, Ewelina
Gruszczyński, Marcin
Lewandowski, Dariusz
Consiglio, Giuseppe
Hreczycho, Grzegorz
author_facet Stachowiak-Dłużyńska, Hanna
Kuciński, Krzysztof
Broniarz, Konstancja
Szafoni, Ewelina
Gruszczyński, Marcin
Lewandowski, Dariusz
Consiglio, Giuseppe
Hreczycho, Grzegorz
author_sort Stachowiak-Dłużyńska, Hanna
collection PubMed
description The reactions between silanols or terminal acetylenes with alkynylgermanes have been accomplished using potassium bis(trimethylsilyl)amide as the catalyst. This strategy has provided an entry point into various organogermanes including germasiloxanes and alkynylgermanes. Remarkably, not only KHMDS but also simple bases such as KOH can serve as efficient catalysts in this process.
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spelling pubmed-100796892023-04-08 Access to germasiloxanes and alkynylgermanes mediated by earth-abundant species Stachowiak-Dłużyńska, Hanna Kuciński, Krzysztof Broniarz, Konstancja Szafoni, Ewelina Gruszczyński, Marcin Lewandowski, Dariusz Consiglio, Giuseppe Hreczycho, Grzegorz Sci Rep Article The reactions between silanols or terminal acetylenes with alkynylgermanes have been accomplished using potassium bis(trimethylsilyl)amide as the catalyst. This strategy has provided an entry point into various organogermanes including germasiloxanes and alkynylgermanes. Remarkably, not only KHMDS but also simple bases such as KOH can serve as efficient catalysts in this process. Nature Publishing Group UK 2023-04-06 /pmc/articles/PMC10079689/ /pubmed/37024548 http://dx.doi.org/10.1038/s41598-023-32172-9 Text en © The Author(s) 2023 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Article
Stachowiak-Dłużyńska, Hanna
Kuciński, Krzysztof
Broniarz, Konstancja
Szafoni, Ewelina
Gruszczyński, Marcin
Lewandowski, Dariusz
Consiglio, Giuseppe
Hreczycho, Grzegorz
Access to germasiloxanes and alkynylgermanes mediated by earth-abundant species
title Access to germasiloxanes and alkynylgermanes mediated by earth-abundant species
title_full Access to germasiloxanes and alkynylgermanes mediated by earth-abundant species
title_fullStr Access to germasiloxanes and alkynylgermanes mediated by earth-abundant species
title_full_unstemmed Access to germasiloxanes and alkynylgermanes mediated by earth-abundant species
title_short Access to germasiloxanes and alkynylgermanes mediated by earth-abundant species
title_sort access to germasiloxanes and alkynylgermanes mediated by earth-abundant species
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10079689/
https://www.ncbi.nlm.nih.gov/pubmed/37024548
http://dx.doi.org/10.1038/s41598-023-32172-9
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