Catalytic, Z-Selective, Semi-Hydrogenation of Alkynes with a Zinc–Anilide Complex

[Image: see text] The reversible activation of dihydrogen with a molecular zinc anilide complex is reported. The mechanism of this reaction has been probed through stoichiometric experiments and density functional theory (DFT) calculations. The combined evidence suggests that H(2) activation occurs...

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Detalles Bibliográficos
Autores principales: Baker, Greg J., White, Andrew J. P., Casely, Ian J., Grainger, Damian, Crimmin, Mark R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10080692/
https://www.ncbi.nlm.nih.gov/pubmed/36972405
http://dx.doi.org/10.1021/jacs.3c02301

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10080692/
https://www.ncbi.nlm.nih.gov/pubmed/36972405
http://dx.doi.org/10.1021/jacs.3c02301

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