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Catalytic, Z-Selective, Semi-Hydrogenation of Alkynes with a Zinc–Anilide Complex
[Image: see text] The reversible activation of dihydrogen with a molecular zinc anilide complex is reported. The mechanism of this reaction has been probed through stoichiometric experiments and density functional theory (DFT) calculations. The combined evidence suggests that H(2) activation occurs...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10080692/ https://www.ncbi.nlm.nih.gov/pubmed/36972405 http://dx.doi.org/10.1021/jacs.3c02301 |