Crystal structure of trimeth­yl({tris­[(phenyl­sulfan­yl)meth­yl]sil­yl}meth­oxy)silane and Hirshfeld surface analysis of 3-bromo-2,2-bis­(bromo­meth­yl)propan-1-ol

Trimeth­yl({tris­[(phenyl­sulfan­yl)meth­yl]sil­yl}meth­oxy)silane (3), C(26)H(32)OS(3)Si, is a new ligand for transition-metal coordination chemistry derived from 3-bromo-2,2-bis­(bromo­meth­yl)propan-1-ol (1), C(5)H(9)Br(3)O, through silylation and following exchange of bromine groups with NaSPh. Silylated thio­ether ligand 3 crystallizes in the centrosymmetric space group C2/c. Bromo­methyl­alcohol 1 crystallizes in the space group P [Image: see text] in the triclinic crystal system with four mol­ecules in the asymmetric unit. Analysis of the Hirshfeld surface shows structure-defining inter­actions for bromo­methyl­alcohol 1, resulting in inter­molecular hydrogen bonds between the hydroxyl groups along the a-axis direction.