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Garnet-type Na(3)Te(2)(FeO(4))(3)

Na(3)Te(2)(FeO(4))(3) or Na(3)Te(2)Fe(3)O(12), tris­odium ditellurium(VI) triiron(III) dodeca­oxide, was obtained in the form of single-crystals under hydro­thermal conditions. Na(3)Te(2)(FeO(4))(3) adopts the garnet structure type in space group Ia [Image: see text] d and comprises one Na (multipli...

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Detalles Bibliográficos
Autores principales: Eder, Felix, Weil, Matthias
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10088310/
https://www.ncbi.nlm.nih.gov/pubmed/37057020
http://dx.doi.org/10.1107/S2056989023002293
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author Eder, Felix
Weil, Matthias
author_facet Eder, Felix
Weil, Matthias
author_sort Eder, Felix
collection PubMed
description Na(3)Te(2)(FeO(4))(3) or Na(3)Te(2)Fe(3)O(12), tris­odium ditellurium(VI) triiron(III) dodeca­oxide, was obtained in the form of single-crystals under hydro­thermal conditions. Na(3)Te(2)(FeO(4))(3) adopts the garnet structure type in space group Ia [Image: see text] d and comprises one Na (multiplicity 24, Wyckoff letter c, site symmetry 2.22), one Te (16 a, . [Image: see text] .), one Fe (24 d, [Image: see text] ..) and one O atom (96 h, 1) in the asymmetric unit. The three-dimensional framework structure is built of [TeO(6)] octa­hedra and [FeO(4)] tetra­hedra by vertex-sharing. The larger Na(+) cations are situated in the inter­stices of the framework and are eightfold coordinated in the form of a distorted dodeca­hedron. Qu­anti­tative structural comparisons with isotypic Na(3)Te(2)[(Fe(0.5)Al(0.5))O(4)](3) and Na(3)Te(2)(GaO(4))(3) show a high degree of similarity between the three crystal structures.
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spelling pubmed-100883102023-04-12 Garnet-type Na(3)Te(2)(FeO(4))(3) Eder, Felix Weil, Matthias Acta Crystallogr E Crystallogr Commun Research Communications Na(3)Te(2)(FeO(4))(3) or Na(3)Te(2)Fe(3)O(12), tris­odium ditellurium(VI) triiron(III) dodeca­oxide, was obtained in the form of single-crystals under hydro­thermal conditions. Na(3)Te(2)(FeO(4))(3) adopts the garnet structure type in space group Ia [Image: see text] d and comprises one Na (multiplicity 24, Wyckoff letter c, site symmetry 2.22), one Te (16 a, . [Image: see text] .), one Fe (24 d, [Image: see text] ..) and one O atom (96 h, 1) in the asymmetric unit. The three-dimensional framework structure is built of [TeO(6)] octa­hedra and [FeO(4)] tetra­hedra by vertex-sharing. The larger Na(+) cations are situated in the inter­stices of the framework and are eightfold coordinated in the form of a distorted dodeca­hedron. Qu­anti­tative structural comparisons with isotypic Na(3)Te(2)[(Fe(0.5)Al(0.5))O(4)](3) and Na(3)Te(2)(GaO(4))(3) show a high degree of similarity between the three crystal structures. International Union of Crystallography 2023-03-15 /pmc/articles/PMC10088310/ /pubmed/37057020 http://dx.doi.org/10.1107/S2056989023002293 Text en © Eder and Weil 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Eder, Felix
Weil, Matthias
Garnet-type Na(3)Te(2)(FeO(4))(3)
title Garnet-type Na(3)Te(2)(FeO(4))(3)
title_full Garnet-type Na(3)Te(2)(FeO(4))(3)
title_fullStr Garnet-type Na(3)Te(2)(FeO(4))(3)
title_full_unstemmed Garnet-type Na(3)Te(2)(FeO(4))(3)
title_short Garnet-type Na(3)Te(2)(FeO(4))(3)
title_sort garnet-type na(3)te(2)(feo(4))(3)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10088310/
https://www.ncbi.nlm.nih.gov/pubmed/37057020
http://dx.doi.org/10.1107/S2056989023002293
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