Crystal structure of [tBuMgCl](2)[MgCl(2)(Et(2)O)(2)](2)

The title compound, di-μ(3)-chlorido-tetra-μ(2)-chlorido-tetra­kis­(diethyl ether-κO)bis­(1,1-di­methyl­eth­yl)tetra­magnesium, [Mg(4)(C(4)H(9))(2)Cl(6)(C(4)H(10)O)(4)], features an Mg(4)Cl(6) open-cube cluster. The two four-coordinate Mg(2+) ions show an almost tetra­hedral coordination, whereas th...

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Detalles Bibliográficos
Autores principales: Metzler, Maurice, Bolte, Michael, Wagner, Matthias, Lerner, Hans-Wolfram
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10088314/
https://www.ncbi.nlm.nih.gov/pubmed/37057008
http://dx.doi.org/10.1107/S2056989023002190
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author Metzler, Maurice
Bolte, Michael
Wagner, Matthias
Lerner, Hans-Wolfram
author_facet Metzler, Maurice
Bolte, Michael
Wagner, Matthias
Lerner, Hans-Wolfram
author_sort Metzler, Maurice
collection PubMed
description The title compound, di-μ(3)-chlorido-tetra-μ(2)-chlorido-tetra­kis­(diethyl ether-κO)bis­(1,1-di­methyl­eth­yl)tetra­magnesium, [Mg(4)(C(4)H(9))(2)Cl(6)(C(4)H(10)O)(4)], features an Mg(4)Cl(6) open-cube cluster. The two four-coordinate Mg(2+) ions show an almost tetra­hedral coordination, whereas the two six-coordinate Mg(2+) ions have their ligands in an octa­hedral environment. The Mg—Cl bond lengths differ depending on the coordination number (2 or 3) of the bridging μ-Cl(−) ligands. There are few comparable structures deposited in the Cambridge Structural Database.
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spelling pubmed-100883142023-04-12 Crystal structure of [tBuMgCl](2)[MgCl(2)(Et(2)O)(2)](2) Metzler, Maurice Bolte, Michael Wagner, Matthias Lerner, Hans-Wolfram Acta Crystallogr E Crystallogr Commun Research Communications The title compound, di-μ(3)-chlorido-tetra-μ(2)-chlorido-tetra­kis­(diethyl ether-κO)bis­(1,1-di­methyl­eth­yl)tetra­magnesium, [Mg(4)(C(4)H(9))(2)Cl(6)(C(4)H(10)O)(4)], features an Mg(4)Cl(6) open-cube cluster. The two four-coordinate Mg(2+) ions show an almost tetra­hedral coordination, whereas the two six-coordinate Mg(2+) ions have their ligands in an octa­hedral environment. The Mg—Cl bond lengths differ depending on the coordination number (2 or 3) of the bridging μ-Cl(−) ligands. There are few comparable structures deposited in the Cambridge Structural Database. International Union of Crystallography 2023-03-15 /pmc/articles/PMC10088314/ /pubmed/37057008 http://dx.doi.org/10.1107/S2056989023002190 Text en © Metzler et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Communications
Metzler, Maurice
Bolte, Michael
Wagner, Matthias
Lerner, Hans-Wolfram
Crystal structure of [tBuMgCl](2)[MgCl(2)(Et(2)O)(2)](2)
title Crystal structure of [tBuMgCl](2)[MgCl(2)(Et(2)O)(2)](2)
title_full Crystal structure of [tBuMgCl](2)[MgCl(2)(Et(2)O)(2)](2)
title_fullStr Crystal structure of [tBuMgCl](2)[MgCl(2)(Et(2)O)(2)](2)
title_full_unstemmed Crystal structure of [tBuMgCl](2)[MgCl(2)(Et(2)O)(2)](2)
title_short Crystal structure of [tBuMgCl](2)[MgCl(2)(Et(2)O)(2)](2)
title_sort crystal structure of [tbumgcl](2)[mgcl(2)(et(2)o)(2)](2)
topic Research Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10088314/
https://www.ncbi.nlm.nih.gov/pubmed/37057008
http://dx.doi.org/10.1107/S2056989023002190
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AT lernerhanswolfram crystalstructureoftbumgcl2mgcl2et2o22

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