Cargando…

A Lewis Acid Stabilized Ketenimine in an Unusual Variant of the Electrophilic Aromatic Substitution

Electrophilic aromatic substitution (EAS) can provide a straightforward approach to the efficient synthesis of functionalized complex aromatic molecules. In general, Lewis acids serve as a beneficial stimulus for the formation of a Wheland complex, the intermediate in the classical S(E)Ar mechanism...

Descripción completa

Detalles Bibliográficos
Autores principales:	Surkau, Jonas, Bläsing, Kevin, Bresien, Jonas, Michalik, Dirk, Villinger, Alexander, Schulz, Axel
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10092272/ https://www.ncbi.nlm.nih.gov/pubmed/35989474 http://dx.doi.org/10.1002/chem.202201905

Ejemplares similares

Azadiphosphaindane‐1,3‐diyls: A Class of Resonance‐Stabilized Biradicals
por: Bresien, Jonas, et al.
Publicado: (2020)

A Phosphorus‐Based Pacman Dication Generated by Cooperative Self‐Activation of a Pacman Phosphane
por: Eickhoff, Liesa, et al.
Publicado: (2021)

A Persistent Phosphanyl‐Substituted Thioketyl Radical Anion
por: Szych, Lilian Sophie, et al.
Publicado: (2022)

Rational Design of Persistent Phosphorus-Centered Singlet Tetraradicals and Their Use in Small-Molecule Activation
por: Zander, Edgar, et al.
Publicado: (2023)

Energetics of Electron Pairs in Electrophilic Aromatic Substitutions
por: Munárriz, Julen, et al.
Publicado: (2021)

High-Level Rovibrational Calculations on Ketenimine
por: Tschöpe, Martin, et al.
Publicado: (2021)

A Systematic Survey of the Reactivity of Chlorinated N(2)P(2), NP(3) and P(4) Ring Systems
por: Bresien, Jonas, et al.
Publicado: (2019)

On Silylated Oxonium and Sulfonium Ions and Their Interaction with Weakly Coordinating Borate Anions
por: Bläsing, Kevin, et al.
Publicado: (2020)

Fast and accurate prediction of the regioselectivity of electrophilic aromatic substitution reactions
por: Kromann, Jimmy C., et al.
Publicado: (2017)

Precise through-space control of an abiotic electrophilic aromatic substitution reaction
por: Murphy, Kyle E., et al.
Publicado: (2017)

RegioSQM20: improved prediction of the regioselectivity of electrophilic aromatic substitutions
por: Ree, Nicolai, et al.
Publicado: (2021)

A chemical reaction controlled by light-activated molecular switches based on hetero-cyclopentanediyls
por: Bresien, Jonas, et al.
Publicado: (2019)

High Site Selectivity in Electrophilic Aromatic Substitutions: Mechanism of C–H Thianthrenation
por: Juliá, Fabio, et al.
Publicado: (2021)

Mechanistic Characterization of Zeolite-Catalyzed Aromatic Electrophilic Substitution at Realistic Operating Conditions
por: Bocus, Massimo, et al.
Publicado: (2022)

Practical synthesis of 3-aryl anthranils via an electrophilic aromatic substitution strategy
por: Gao, Yang, et al.
Publicado: (2022)

Synthesis of Highly Reactive Ketenimines via Photochemical Rearrangement of Isoxazoles
por: Bracken, Cormac, et al.
Publicado: (2023)

A versatile route to edge-specific modifications to pristine graphene by electrophilic aromatic substitution
por: Shellard, Philippa M., et al.
Publicado: (2020)

Radical Reactivity of the Biradical [⋅P(μ‐NTer)(2)P⋅] and Isolation of a Persistent Phosphorus‐Cantered Monoradical [⋅P(μ‐NTer)(2)P‐Et]
por: Rosenboom, Jan, et al.
Publicado: (2022)

Prediction of the Synthesis of Spiro Derivatives by Double Intramolecular Aromatic Electrophilic Substitution Using Reactivity Indices
por: Dalinot, Clément, et al.
Publicado: (2019)

Silylated Sulfuric Acid: Preparation of a Tris(trimethylsilyl)oxosulfonium [(Me(3)Si−O)(3)SO](+) Salt
por: Bläsing, Kevin, et al.
Publicado: (2021)

Pseudohalogen Chemistry in Ionic Liquids with Non‐innocent Cations and Anions
por: Arlt, Sören, et al.
Publicado: (2020)

Copper-catalyzed Z-selective synthesis of acrylamides and polyacrylamides via alkylidene ketenimines
por: Duan, Xuelun, et al.
Publicado: (2022)

Desulfination by 2′-hydroxybiphenyl-2-sulfinate desulfinase proceeds via electrophilic aromatic substitution by the cysteine-27 proton
por: Geronimo, Inacrist, et al.
Publicado: (2017)

Synthesis of 1-Silabenzo[d,e]isochromanes via Electrophilic Aromatic Substitution of Aldehydes Activated by Silylium Ion
por: Arii, Hidekazu, et al.
Publicado: (2022)

Analogy of the Reactions of Aromatic and Aliphatic π-Electrophiles with Nucleophiles
por: Barbasiewicz, Michał, et al.
Publicado: (2023)

Parahydrogen-induced polarization with a metal-free P–P biradicaloid
por: Zhivonitko, Vladimir V., et al.
Publicado: (2019)

Investigation into the Semantic Density and Semantic Gravity Wave Profile of Teachers When Discussing Electrophilic Aromatic Substitution (S(E)Ar)
por: Cranwell, Philippa B., et al.
Publicado: (2020)

Electrophilic bis-fluorophosphonium dications: Lewis acid catalysts from diphosphines
por: Holthausen, Michael H., et al.
Publicado: (2015)

Lewis Superacidic Tellurenyl Cation‐Induced Electrophilic Activation of an Inert Carborane
por: Hejda, Martin, et al.
Publicado: (2021)

Regioselective Electrophilic Aromatic Bromination: Theoretical Analysis and Experimental Verification
por: Li, Hui-Jing, et al.
Publicado: (2014)

Salts of HCN‐Cyanide Aggregates: [CN(HCN)(2)](−) and [CN(HCN)(3)](−)
por: Bläsing, Kevin, et al.
Publicado: (2020)

Blue Light-Promoted Cross-Coupling of α-Diazo Esters with Isocyanides: Synthesis of Ester-Functionalized Ketenimines
por: Sakharov, Pavel A., et al.
Publicado: (2022)

Effect of Aromatic Substitution of Curcumin Nanoformulations on Their Stability
por: Okonogi, Siriporn, et al.
Publicado: (2016)

Synthesis of Functional Fluorescent BODIPY‐based Dyes through Electrophilic Aromatic Substitution: Straightforward Approach towards Customized Fluorescent Probes
por: Mirri, Giorgio, et al.
Publicado: (2016)

Catalyst-Free Site Selective Hydroxyalkylation of 5-Phenylthiophen-2-amine with α-Trifluoromethyl Ketones through Electrophilic Aromatic Substitution
por: Duvauchelle, Valentin, et al.
Publicado: (2022)

Hyperpolarization Effects in Parahydrogen Activation with Pnictogen Biradicaloids: Metal‐free PHIP and SABRE
por: Zhivonitko, Vladimir V., et al.
Publicado: (2021)

Design and Synthesis of Ketenimine Sulfonamide Conjugates through Multicomponent Reactions; A Combined Cytotoxic Analysis and Computational Exploration
por: Prabhu, Deepak J., et al.
Publicado: (2023)

Enantioselective alkylative cross-coupling of unactivated aromatic C–O electrophiles
por: Zhang, Zishuo, et al.
Publicado: (2022)

How Do Aromatic Nitro Compounds React with Nucleophiles? Theoretical Description Using Aromaticity, Nucleophilicity and Electrophilicity Indices
por: Błaziak, Kacper, et al.
Publicado: (2020)

Cleavage of non-polar C(sp(2))‒C(sp(2)) bonds in cycloparaphenylenes via electric field-catalyzed electrophilic aromatic substitution
por: Lin, Junfeng, et al.
Publicado: (2023)

Cannot write session to /tmp/vufind_sessions/sess_t27clfaqltfqosl51f1m703qk4