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Control of the assembly of a cyclic hetero[4]pseudorotaxane from a self-complementary [2]rotaxane

The synthesis of a ditopic interlocked building-block and its self-assembly into a cyclic dimer is reported herein. Starting from a thread with two recognition sites, a three-component clipping reaction was carried out to construct a bistable [2]rotaxane. A subsequent Suzuki cross-coupling reaction...

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Detalles Bibliográficos
Autores principales: Saura-Sanmartin, Adrian, Nicolas-Garcia, Tomas, Pastor, Aurelia, Quiñonero, David, Alajarin, Mateo, Martinez-Cuezva, Alberto, Berna, Jose
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10094293/
https://www.ncbi.nlm.nih.gov/pubmed/37063802
http://dx.doi.org/10.1039/d3sc00886j

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