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Porous Polymers Based on 9,10-Bis(methacryloyloxymethyl)anthracene—Towards Synthesis and Characterization

Porous materials can be found in numerous essential applications. They are of particular interest when, in addition to their porosity, they have other advantageous properties such as thermal stability or chemical diversity. The main aim of this study was to synthesize the porous copolymers of 9,10-b...

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Autores principales: Maciejewska, Małgorzata, Józwicki, Mateusz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10095706/
https://www.ncbi.nlm.nih.gov/pubmed/37048904
http://dx.doi.org/10.3390/ma16072610
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author Maciejewska, Małgorzata
Józwicki, Mateusz
author_facet Maciejewska, Małgorzata
Józwicki, Mateusz
author_sort Maciejewska, Małgorzata
collection PubMed
description Porous materials can be found in numerous essential applications. They are of particular interest when, in addition to their porosity, they have other advantageous properties such as thermal stability or chemical diversity. The main aim of this study was to synthesize the porous copolymers of 9,10-bis(methacryloyloxymethyl)anthracene (BMA) with three different co-monomers divinylbenzene (DVB), ethylene glycol dimethacrylate (EGDMA) and trimethylpropane trimethacrylate (TRIM). They were synthesized via suspension polymerization using chlorobenzene and toluene served as porogenic solvents. For the characterization of the synthesized copolymers ATR-FTIR spectroscopy, a low-temperature nitrogen adsorption–desorption method, thermogravimetry, scanning electron microscopy, inverse gas chromatography and size distribution analysis were successfully employed. It was found that depending on the used co-monomer and the type of porogen regular polymeric microspheres with a specific surface area in the range of 134–472 m(2)/g can be effectively synthesized. The presence of miscellaneous functional groups promotes divergent types of interactions Moreover, all of the copolymers show a good thermal stability up to 307 °C. What is important, thanks to application of anthracene derivatives as the functional monomer, the synthesized materials show fluorescence under UV radiation. The obtained microspheres can be used in various adsorption techniques as well as precursor for thermally resistant fluorescent sensors.
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spelling pubmed-100957062023-04-13 Porous Polymers Based on 9,10-Bis(methacryloyloxymethyl)anthracene—Towards Synthesis and Characterization Maciejewska, Małgorzata Józwicki, Mateusz Materials (Basel) Article Porous materials can be found in numerous essential applications. They are of particular interest when, in addition to their porosity, they have other advantageous properties such as thermal stability or chemical diversity. The main aim of this study was to synthesize the porous copolymers of 9,10-bis(methacryloyloxymethyl)anthracene (BMA) with three different co-monomers divinylbenzene (DVB), ethylene glycol dimethacrylate (EGDMA) and trimethylpropane trimethacrylate (TRIM). They were synthesized via suspension polymerization using chlorobenzene and toluene served as porogenic solvents. For the characterization of the synthesized copolymers ATR-FTIR spectroscopy, a low-temperature nitrogen adsorption–desorption method, thermogravimetry, scanning electron microscopy, inverse gas chromatography and size distribution analysis were successfully employed. It was found that depending on the used co-monomer and the type of porogen regular polymeric microspheres with a specific surface area in the range of 134–472 m(2)/g can be effectively synthesized. The presence of miscellaneous functional groups promotes divergent types of interactions Moreover, all of the copolymers show a good thermal stability up to 307 °C. What is important, thanks to application of anthracene derivatives as the functional monomer, the synthesized materials show fluorescence under UV radiation. The obtained microspheres can be used in various adsorption techniques as well as precursor for thermally resistant fluorescent sensors. MDPI 2023-03-25 /pmc/articles/PMC10095706/ /pubmed/37048904 http://dx.doi.org/10.3390/ma16072610 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Maciejewska, Małgorzata
Józwicki, Mateusz
Porous Polymers Based on 9,10-Bis(methacryloyloxymethyl)anthracene—Towards Synthesis and Characterization
title Porous Polymers Based on 9,10-Bis(methacryloyloxymethyl)anthracene—Towards Synthesis and Characterization
title_full Porous Polymers Based on 9,10-Bis(methacryloyloxymethyl)anthracene—Towards Synthesis and Characterization
title_fullStr Porous Polymers Based on 9,10-Bis(methacryloyloxymethyl)anthracene—Towards Synthesis and Characterization
title_full_unstemmed Porous Polymers Based on 9,10-Bis(methacryloyloxymethyl)anthracene—Towards Synthesis and Characterization
title_short Porous Polymers Based on 9,10-Bis(methacryloyloxymethyl)anthracene—Towards Synthesis and Characterization
title_sort porous polymers based on 9,10-bis(methacryloyloxymethyl)anthracene—towards synthesis and characterization
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10095706/
https://www.ncbi.nlm.nih.gov/pubmed/37048904
http://dx.doi.org/10.3390/ma16072610
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