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Porous Polymers Based on 9,10-Bis(methacryloyloxymethyl)anthracene—Towards Synthesis and Characterization
Porous materials can be found in numerous essential applications. They are of particular interest when, in addition to their porosity, they have other advantageous properties such as thermal stability or chemical diversity. The main aim of this study was to synthesize the porous copolymers of 9,10-b...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10095706/ https://www.ncbi.nlm.nih.gov/pubmed/37048904 http://dx.doi.org/10.3390/ma16072610 |
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author | Maciejewska, Małgorzata Józwicki, Mateusz |
author_facet | Maciejewska, Małgorzata Józwicki, Mateusz |
author_sort | Maciejewska, Małgorzata |
collection | PubMed |
description | Porous materials can be found in numerous essential applications. They are of particular interest when, in addition to their porosity, they have other advantageous properties such as thermal stability or chemical diversity. The main aim of this study was to synthesize the porous copolymers of 9,10-bis(methacryloyloxymethyl)anthracene (BMA) with three different co-monomers divinylbenzene (DVB), ethylene glycol dimethacrylate (EGDMA) and trimethylpropane trimethacrylate (TRIM). They were synthesized via suspension polymerization using chlorobenzene and toluene served as porogenic solvents. For the characterization of the synthesized copolymers ATR-FTIR spectroscopy, a low-temperature nitrogen adsorption–desorption method, thermogravimetry, scanning electron microscopy, inverse gas chromatography and size distribution analysis were successfully employed. It was found that depending on the used co-monomer and the type of porogen regular polymeric microspheres with a specific surface area in the range of 134–472 m(2)/g can be effectively synthesized. The presence of miscellaneous functional groups promotes divergent types of interactions Moreover, all of the copolymers show a good thermal stability up to 307 °C. What is important, thanks to application of anthracene derivatives as the functional monomer, the synthesized materials show fluorescence under UV radiation. The obtained microspheres can be used in various adsorption techniques as well as precursor for thermally resistant fluorescent sensors. |
format | Online Article Text |
id | pubmed-10095706 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-100957062023-04-13 Porous Polymers Based on 9,10-Bis(methacryloyloxymethyl)anthracene—Towards Synthesis and Characterization Maciejewska, Małgorzata Józwicki, Mateusz Materials (Basel) Article Porous materials can be found in numerous essential applications. They are of particular interest when, in addition to their porosity, they have other advantageous properties such as thermal stability or chemical diversity. The main aim of this study was to synthesize the porous copolymers of 9,10-bis(methacryloyloxymethyl)anthracene (BMA) with three different co-monomers divinylbenzene (DVB), ethylene glycol dimethacrylate (EGDMA) and trimethylpropane trimethacrylate (TRIM). They were synthesized via suspension polymerization using chlorobenzene and toluene served as porogenic solvents. For the characterization of the synthesized copolymers ATR-FTIR spectroscopy, a low-temperature nitrogen adsorption–desorption method, thermogravimetry, scanning electron microscopy, inverse gas chromatography and size distribution analysis were successfully employed. It was found that depending on the used co-monomer and the type of porogen regular polymeric microspheres with a specific surface area in the range of 134–472 m(2)/g can be effectively synthesized. The presence of miscellaneous functional groups promotes divergent types of interactions Moreover, all of the copolymers show a good thermal stability up to 307 °C. What is important, thanks to application of anthracene derivatives as the functional monomer, the synthesized materials show fluorescence under UV radiation. The obtained microspheres can be used in various adsorption techniques as well as precursor for thermally resistant fluorescent sensors. MDPI 2023-03-25 /pmc/articles/PMC10095706/ /pubmed/37048904 http://dx.doi.org/10.3390/ma16072610 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Maciejewska, Małgorzata Józwicki, Mateusz Porous Polymers Based on 9,10-Bis(methacryloyloxymethyl)anthracene—Towards Synthesis and Characterization |
title | Porous Polymers Based on 9,10-Bis(methacryloyloxymethyl)anthracene—Towards Synthesis and Characterization |
title_full | Porous Polymers Based on 9,10-Bis(methacryloyloxymethyl)anthracene—Towards Synthesis and Characterization |
title_fullStr | Porous Polymers Based on 9,10-Bis(methacryloyloxymethyl)anthracene—Towards Synthesis and Characterization |
title_full_unstemmed | Porous Polymers Based on 9,10-Bis(methacryloyloxymethyl)anthracene—Towards Synthesis and Characterization |
title_short | Porous Polymers Based on 9,10-Bis(methacryloyloxymethyl)anthracene—Towards Synthesis and Characterization |
title_sort | porous polymers based on 9,10-bis(methacryloyloxymethyl)anthracene—towards synthesis and characterization |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10095706/ https://www.ncbi.nlm.nih.gov/pubmed/37048904 http://dx.doi.org/10.3390/ma16072610 |
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