Accelerated Synthesis of Borophane (HB) Sheets through HCl-Assisted Ion-Exchange Reaction with YCrB(4)

We present an enhanced method for synthesizing sheets of borophane. Despite the challenges associated with low efficiency, we discovered that incorporating hydrochloric acid into the ion-exchange reaction significantly improved the production yield from 20% to over 50%. After a thorough examination...

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Detalles Bibliográficos
Autores principales: Zhang, Xiaoni, Hikichi, Miwa, Iimori, Takushi, Tsujikawa, Yuki, Yuan, Mei, Horio, Masafumi, Yubuta, Kunio, Komori, Fumio, Miyauchi, Masahiro, Kondo, Takahiro, Matsuda, Iwao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10096318/
https://www.ncbi.nlm.nih.gov/pubmed/37049748
http://dx.doi.org/10.3390/molecules28072985
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author Zhang, Xiaoni
Hikichi, Miwa
Iimori, Takushi
Tsujikawa, Yuki
Yuan, Mei
Horio, Masafumi
Yubuta, Kunio
Komori, Fumio
Miyauchi, Masahiro
Kondo, Takahiro
Matsuda, Iwao
author_facet Zhang, Xiaoni
Hikichi, Miwa
Iimori, Takushi
Tsujikawa, Yuki
Yuan, Mei
Horio, Masafumi
Yubuta, Kunio
Komori, Fumio
Miyauchi, Masahiro
Kondo, Takahiro
Matsuda, Iwao
author_sort Zhang, Xiaoni
collection PubMed
description We present an enhanced method for synthesizing sheets of borophane. Despite the challenges associated with low efficiency, we discovered that incorporating hydrochloric acid into the ion-exchange reaction significantly improved the production yield from 20% to over 50%. After a thorough examination of the reaction, we gained insight into the underlying mechanisms and found that the use of hydrochloric acid provides two key benefits: accelerated production of borophene and isolation of high-purity products. This method has the potential to pave the way for the production of novel topological 2D materials with potential industrial applications.
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spelling pubmed-100963182023-04-13 Accelerated Synthesis of Borophane (HB) Sheets through HCl-Assisted Ion-Exchange Reaction with YCrB(4) Zhang, Xiaoni Hikichi, Miwa Iimori, Takushi Tsujikawa, Yuki Yuan, Mei Horio, Masafumi Yubuta, Kunio Komori, Fumio Miyauchi, Masahiro Kondo, Takahiro Matsuda, Iwao Molecules Article We present an enhanced method for synthesizing sheets of borophane. Despite the challenges associated with low efficiency, we discovered that incorporating hydrochloric acid into the ion-exchange reaction significantly improved the production yield from 20% to over 50%. After a thorough examination of the reaction, we gained insight into the underlying mechanisms and found that the use of hydrochloric acid provides two key benefits: accelerated production of borophene and isolation of high-purity products. This method has the potential to pave the way for the production of novel topological 2D materials with potential industrial applications. MDPI 2023-03-27 /pmc/articles/PMC10096318/ /pubmed/37049748 http://dx.doi.org/10.3390/molecules28072985 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Zhang, Xiaoni
Hikichi, Miwa
Iimori, Takushi
Tsujikawa, Yuki
Yuan, Mei
Horio, Masafumi
Yubuta, Kunio
Komori, Fumio
Miyauchi, Masahiro
Kondo, Takahiro
Matsuda, Iwao
Accelerated Synthesis of Borophane (HB) Sheets through HCl-Assisted Ion-Exchange Reaction with YCrB(4)
title Accelerated Synthesis of Borophane (HB) Sheets through HCl-Assisted Ion-Exchange Reaction with YCrB(4)
title_full Accelerated Synthesis of Borophane (HB) Sheets through HCl-Assisted Ion-Exchange Reaction with YCrB(4)
title_fullStr Accelerated Synthesis of Borophane (HB) Sheets through HCl-Assisted Ion-Exchange Reaction with YCrB(4)
title_full_unstemmed Accelerated Synthesis of Borophane (HB) Sheets through HCl-Assisted Ion-Exchange Reaction with YCrB(4)
title_short Accelerated Synthesis of Borophane (HB) Sheets through HCl-Assisted Ion-Exchange Reaction with YCrB(4)
title_sort accelerated synthesis of borophane (hb) sheets through hcl-assisted ion-exchange reaction with ycrb(4)
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10096318/
https://www.ncbi.nlm.nih.gov/pubmed/37049748
http://dx.doi.org/10.3390/molecules28072985
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