Cargando…
Synthesis of Tetrasubstituted Nitroalkenes and Preliminary Studies of Their Enantioselective Organocatalytic Reduction
Starting from commercially available ketones, a reproducible and reliable strategy for the synthesis of tetrasubstituted nitroalkenes was successfully developed, using a two-step procedure; the HWE olefination of the ketone to form the corresponding α,β-unsaturated esters is followed by a nitration...
Autores principales: | González, Patricia Camarero, Rossi, Sergio, Sanz, Miguel, Vasile, Francesca, Benaglia, Maurizio |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10096420/ https://www.ncbi.nlm.nih.gov/pubmed/37049919 http://dx.doi.org/10.3390/molecules28073156 |
Ejemplares similares
-
Nitroalkene reduction in deep eutectic solvents promoted by BH(3)NH(3)
por: Faverio, Chiara, et al.
Publicado: (2021) -
Organocatalytic Michael Addition to (D)-Mannitol-Derived Enantiopure Nitroalkenes: A Valuable Strategy for the Synthesis of Densely Functionalized Chiral Molecules
por: Caruso, Lucia, et al.
Publicado: (2019) -
Organocatalytic synthesis of chiral tetrasubstituted allenes from racemic propargylic alcohols
por: Qian, Deyun, et al.
Publicado: (2017) -
Organocatalytic Asymmetric Conjugate Addition of Aldehydes to Maleimides and Nitroalkenes in Deep Eutectic Solvents
por: Torregrosa-Chinillach, Alejandro, et al.
Publicado: (2019) -
Organocatalytic and enantioselective Michael reaction between α-nitroesters and nitroalkenes. Syn/anti-selectivity control using catalysts with the same absolute backbone chirality
por: Martínez, Jose I, et al.
Publicado: (2015)