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Optoelectrical Properties of Hexamine Doped-Methylammonium Lead Iodide Perovskite under Different Grain-Shape Crystallinity

The crystallinity properties of perovskite influence their optoelectrical performance in solar cell applications. We optimized the grain shape and crystallinity of perovskite film by annealing treatment from 130 to 170 °C under high humidity (relative humidity of 70%). We found that the grain size,...

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Autores principales: Ali Umar, Marjoni Imamora, Ahdaliza, Annisa Zahra, El-Bahy, Salah M., Aliza, Nur, Sadikin, Siti Naqiyah, Ridwan, Jaenudin, Ehsan, Abang Annuar, Amin, Mohammed A., El-Bahy, Zeinhom M., Ali Umar, Akrajas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10096868/
https://www.ncbi.nlm.nih.gov/pubmed/37049374
http://dx.doi.org/10.3390/nano13071281
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author Ali Umar, Marjoni Imamora
Ahdaliza, Annisa Zahra
El-Bahy, Salah M.
Aliza, Nur
Sadikin, Siti Naqiyah
Ridwan, Jaenudin
Ehsan, Abang Annuar
Amin, Mohammed A.
El-Bahy, Zeinhom M.
Ali Umar, Akrajas
author_facet Ali Umar, Marjoni Imamora
Ahdaliza, Annisa Zahra
El-Bahy, Salah M.
Aliza, Nur
Sadikin, Siti Naqiyah
Ridwan, Jaenudin
Ehsan, Abang Annuar
Amin, Mohammed A.
El-Bahy, Zeinhom M.
Ali Umar, Akrajas
author_sort Ali Umar, Marjoni Imamora
collection PubMed
description The crystallinity properties of perovskite influence their optoelectrical performance in solar cell applications. We optimized the grain shape and crystallinity of perovskite film by annealing treatment from 130 to 170 °C under high humidity (relative humidity of 70%). We found that the grain size, grain interface, and grain morphology of the perovskite are optimized when the sample was annealed at 150 °C for 1 h in the air. At this condition, the perovskite film is composed of 250 nm crystalline shape grain and compact inter-grain structure with an invincible grain interface. Perovskite solar cells device analysis indicated that the device fabricated using the samples annealed at 150 °C produced the highest power conversion efficiency, namely 17.77%. The open circuit voltage (V(oc)), short-circuit current density (J(sc)), and fill factor (FF) of the device are as high as 1.05 V, 22.27 mA/cm(2), and 0.76, respectively. Optoelectrical dynamic analysis using transient photoluminescence and electrochemical impedance spectroscopies reveals that (i) carrier lifetime in the champion device can be up to 25 ns, which is almost double the carrier lifetime of the sample annealed at 130 °C. (ii) The interfacial charge transfer resistance is low in the champion device, i.e., ~20 Ω, which has a crystalline grain morphology, enabling active photocurrent extraction. Perovskite’s behavior under annealing treatment in high humidity conditions can be a guide for the industrialization of perovskite solar cells.
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spelling pubmed-100968682023-04-13 Optoelectrical Properties of Hexamine Doped-Methylammonium Lead Iodide Perovskite under Different Grain-Shape Crystallinity Ali Umar, Marjoni Imamora Ahdaliza, Annisa Zahra El-Bahy, Salah M. Aliza, Nur Sadikin, Siti Naqiyah Ridwan, Jaenudin Ehsan, Abang Annuar Amin, Mohammed A. El-Bahy, Zeinhom M. Ali Umar, Akrajas Nanomaterials (Basel) Article The crystallinity properties of perovskite influence their optoelectrical performance in solar cell applications. We optimized the grain shape and crystallinity of perovskite film by annealing treatment from 130 to 170 °C under high humidity (relative humidity of 70%). We found that the grain size, grain interface, and grain morphology of the perovskite are optimized when the sample was annealed at 150 °C for 1 h in the air. At this condition, the perovskite film is composed of 250 nm crystalline shape grain and compact inter-grain structure with an invincible grain interface. Perovskite solar cells device analysis indicated that the device fabricated using the samples annealed at 150 °C produced the highest power conversion efficiency, namely 17.77%. The open circuit voltage (V(oc)), short-circuit current density (J(sc)), and fill factor (FF) of the device are as high as 1.05 V, 22.27 mA/cm(2), and 0.76, respectively. Optoelectrical dynamic analysis using transient photoluminescence and electrochemical impedance spectroscopies reveals that (i) carrier lifetime in the champion device can be up to 25 ns, which is almost double the carrier lifetime of the sample annealed at 130 °C. (ii) The interfacial charge transfer resistance is low in the champion device, i.e., ~20 Ω, which has a crystalline grain morphology, enabling active photocurrent extraction. Perovskite’s behavior under annealing treatment in high humidity conditions can be a guide for the industrialization of perovskite solar cells. MDPI 2023-04-05 /pmc/articles/PMC10096868/ /pubmed/37049374 http://dx.doi.org/10.3390/nano13071281 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Ali Umar, Marjoni Imamora
Ahdaliza, Annisa Zahra
El-Bahy, Salah M.
Aliza, Nur
Sadikin, Siti Naqiyah
Ridwan, Jaenudin
Ehsan, Abang Annuar
Amin, Mohammed A.
El-Bahy, Zeinhom M.
Ali Umar, Akrajas
Optoelectrical Properties of Hexamine Doped-Methylammonium Lead Iodide Perovskite under Different Grain-Shape Crystallinity
title Optoelectrical Properties of Hexamine Doped-Methylammonium Lead Iodide Perovskite under Different Grain-Shape Crystallinity
title_full Optoelectrical Properties of Hexamine Doped-Methylammonium Lead Iodide Perovskite under Different Grain-Shape Crystallinity
title_fullStr Optoelectrical Properties of Hexamine Doped-Methylammonium Lead Iodide Perovskite under Different Grain-Shape Crystallinity
title_full_unstemmed Optoelectrical Properties of Hexamine Doped-Methylammonium Lead Iodide Perovskite under Different Grain-Shape Crystallinity
title_short Optoelectrical Properties of Hexamine Doped-Methylammonium Lead Iodide Perovskite under Different Grain-Shape Crystallinity
title_sort optoelectrical properties of hexamine doped-methylammonium lead iodide perovskite under different grain-shape crystallinity
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10096868/
https://www.ncbi.nlm.nih.gov/pubmed/37049374
http://dx.doi.org/10.3390/nano13071281
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