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H(2)O(2) Solution Steaming Combined Method to Cellulose Skeleton for Transparent Wood Infiltrated with Cellulose Acetate
Hydrogen peroxide (H(2)O(2)) steaming, a green and highly efficient delignification method, has been demonstrated to provide a wood skeleton with a very low content of residual lignin in the manufacturing of transparent wood. It usually requires a long reaction time and a large amount of H(2)O(2) be...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10097299/ https://www.ncbi.nlm.nih.gov/pubmed/37050347 http://dx.doi.org/10.3390/polym15071733 |
Sumario: | Hydrogen peroxide (H(2)O(2)) steaming, a green and highly efficient delignification method, has been demonstrated to provide a wood skeleton with a very low content of residual lignin in the manufacturing of transparent wood. It usually requires a long reaction time and a large amount of H(2)O(2) because the piece of wood is treated using steaming equipment. Herein, a H(2)O(2) solution steaming method was developed for the highly efficient removal of lignin from wood. Specifically, several wood samples were simultaneously immersed in a hot H(2)O(2) solution to obtain delignified wood with a relatively high content of residual lignin, which provided a high strength and preserved the cellulose skeleton. Subsequently, the delignified wood with a relatively high content of residual lignin was further treated with H(2)O(2) steam to obtain a very low lignin delignified wood. Compared with the previous H(2)O(2) steaming method, the reaction time and used H(2)O(2) volume of the H(2)O(2) solution steaming method was reduced by 37.3% and 52.7%, respectively. All-biomass transparent wood could be obtained by infiltrating the delignified wood with cellulose acetate, which showed both a high transmittance of 83.0% and a low thermal conductivity of 0.30 Wm(−1)K(−1). |
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