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H(2)O(2) Solution Steaming Combined Method to Cellulose Skeleton for Transparent Wood Infiltrated with Cellulose Acetate

Hydrogen peroxide (H(2)O(2)) steaming, a green and highly efficient delignification method, has been demonstrated to provide a wood skeleton with a very low content of residual lignin in the manufacturing of transparent wood. It usually requires a long reaction time and a large amount of H(2)O(2) be...

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Detalles Bibliográficos
Autores principales: Zhang, Jun, Ying, Yongling, Yi, Xiaoyang, Han, Wenbo, Yin, Lu, Zheng, Yongjun, Zheng, Rongbo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10097299/
https://www.ncbi.nlm.nih.gov/pubmed/37050347
http://dx.doi.org/10.3390/polym15071733
Descripción
Sumario:Hydrogen peroxide (H(2)O(2)) steaming, a green and highly efficient delignification method, has been demonstrated to provide a wood skeleton with a very low content of residual lignin in the manufacturing of transparent wood. It usually requires a long reaction time and a large amount of H(2)O(2) because the piece of wood is treated using steaming equipment. Herein, a H(2)O(2) solution steaming method was developed for the highly efficient removal of lignin from wood. Specifically, several wood samples were simultaneously immersed in a hot H(2)O(2) solution to obtain delignified wood with a relatively high content of residual lignin, which provided a high strength and preserved the cellulose skeleton. Subsequently, the delignified wood with a relatively high content of residual lignin was further treated with H(2)O(2) steam to obtain a very low lignin delignified wood. Compared with the previous H(2)O(2) steaming method, the reaction time and used H(2)O(2) volume of the H(2)O(2) solution steaming method was reduced by 37.3% and 52.7%, respectively. All-biomass transparent wood could be obtained by infiltrating the delignified wood with cellulose acetate, which showed both a high transmittance of 83.0% and a low thermal conductivity of 0.30 Wm(−1)K(−1).