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H(2)O(2) Solution Steaming Combined Method to Cellulose Skeleton for Transparent Wood Infiltrated with Cellulose Acetate

Hydrogen peroxide (H(2)O(2)) steaming, a green and highly efficient delignification method, has been demonstrated to provide a wood skeleton with a very low content of residual lignin in the manufacturing of transparent wood. It usually requires a long reaction time and a large amount of H(2)O(2) be...

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Autores principales: Zhang, Jun, Ying, Yongling, Yi, Xiaoyang, Han, Wenbo, Yin, Lu, Zheng, Yongjun, Zheng, Rongbo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10097299/
https://www.ncbi.nlm.nih.gov/pubmed/37050347
http://dx.doi.org/10.3390/polym15071733
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author Zhang, Jun
Ying, Yongling
Yi, Xiaoyang
Han, Wenbo
Yin, Lu
Zheng, Yongjun
Zheng, Rongbo
author_facet Zhang, Jun
Ying, Yongling
Yi, Xiaoyang
Han, Wenbo
Yin, Lu
Zheng, Yongjun
Zheng, Rongbo
author_sort Zhang, Jun
collection PubMed
description Hydrogen peroxide (H(2)O(2)) steaming, a green and highly efficient delignification method, has been demonstrated to provide a wood skeleton with a very low content of residual lignin in the manufacturing of transparent wood. It usually requires a long reaction time and a large amount of H(2)O(2) because the piece of wood is treated using steaming equipment. Herein, a H(2)O(2) solution steaming method was developed for the highly efficient removal of lignin from wood. Specifically, several wood samples were simultaneously immersed in a hot H(2)O(2) solution to obtain delignified wood with a relatively high content of residual lignin, which provided a high strength and preserved the cellulose skeleton. Subsequently, the delignified wood with a relatively high content of residual lignin was further treated with H(2)O(2) steam to obtain a very low lignin delignified wood. Compared with the previous H(2)O(2) steaming method, the reaction time and used H(2)O(2) volume of the H(2)O(2) solution steaming method was reduced by 37.3% and 52.7%, respectively. All-biomass transparent wood could be obtained by infiltrating the delignified wood with cellulose acetate, which showed both a high transmittance of 83.0% and a low thermal conductivity of 0.30 Wm(−1)K(−1).
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spelling pubmed-100972992023-04-13 H(2)O(2) Solution Steaming Combined Method to Cellulose Skeleton for Transparent Wood Infiltrated with Cellulose Acetate Zhang, Jun Ying, Yongling Yi, Xiaoyang Han, Wenbo Yin, Lu Zheng, Yongjun Zheng, Rongbo Polymers (Basel) Article Hydrogen peroxide (H(2)O(2)) steaming, a green and highly efficient delignification method, has been demonstrated to provide a wood skeleton with a very low content of residual lignin in the manufacturing of transparent wood. It usually requires a long reaction time and a large amount of H(2)O(2) because the piece of wood is treated using steaming equipment. Herein, a H(2)O(2) solution steaming method was developed for the highly efficient removal of lignin from wood. Specifically, several wood samples were simultaneously immersed in a hot H(2)O(2) solution to obtain delignified wood with a relatively high content of residual lignin, which provided a high strength and preserved the cellulose skeleton. Subsequently, the delignified wood with a relatively high content of residual lignin was further treated with H(2)O(2) steam to obtain a very low lignin delignified wood. Compared with the previous H(2)O(2) steaming method, the reaction time and used H(2)O(2) volume of the H(2)O(2) solution steaming method was reduced by 37.3% and 52.7%, respectively. All-biomass transparent wood could be obtained by infiltrating the delignified wood with cellulose acetate, which showed both a high transmittance of 83.0% and a low thermal conductivity of 0.30 Wm(−1)K(−1). MDPI 2023-03-31 /pmc/articles/PMC10097299/ /pubmed/37050347 http://dx.doi.org/10.3390/polym15071733 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Zhang, Jun
Ying, Yongling
Yi, Xiaoyang
Han, Wenbo
Yin, Lu
Zheng, Yongjun
Zheng, Rongbo
H(2)O(2) Solution Steaming Combined Method to Cellulose Skeleton for Transparent Wood Infiltrated with Cellulose Acetate
title H(2)O(2) Solution Steaming Combined Method to Cellulose Skeleton for Transparent Wood Infiltrated with Cellulose Acetate
title_full H(2)O(2) Solution Steaming Combined Method to Cellulose Skeleton for Transparent Wood Infiltrated with Cellulose Acetate
title_fullStr H(2)O(2) Solution Steaming Combined Method to Cellulose Skeleton for Transparent Wood Infiltrated with Cellulose Acetate
title_full_unstemmed H(2)O(2) Solution Steaming Combined Method to Cellulose Skeleton for Transparent Wood Infiltrated with Cellulose Acetate
title_short H(2)O(2) Solution Steaming Combined Method to Cellulose Skeleton for Transparent Wood Infiltrated with Cellulose Acetate
title_sort h(2)o(2) solution steaming combined method to cellulose skeleton for transparent wood infiltrated with cellulose acetate
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10097299/
https://www.ncbi.nlm.nih.gov/pubmed/37050347
http://dx.doi.org/10.3390/polym15071733
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