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Isolation and Reactivity of Stannylenoids Stabilized by Amido/Imino Ligands

The reaction of the lithium aryl(silyl)amide Dipp(( i )Pr(3)Si)NLi (Dipp=2,6‐( i )Pr(2)C(6)H(3)) with one equivalent of SnCl(2) in THF gave a novel stannylenoid Dipp(( i )Pr(3)Si)NSnCl⋅LiCl(THF)(2). Heating the solution of amidostannylenoid in toluene to 80 °C resulted in dimeric amido(chloro)stanny...

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Detalles Bibliográficos
Autores principales: Zhao, Xuan‐Xuan, Fujimori, Shiori, Kelly, John A., Inoue, Shigeyoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10098732/
https://www.ncbi.nlm.nih.gov/pubmed/36195558
http://dx.doi.org/10.1002/chem.202202712

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