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Critical Properties of Ternary Deep Eutectic Solvents Using Group Contribution with Extended Lee–Kesler Mixing Rules
[Image: see text] One of the most commonly used molecular inputs for ionic liquids and deep eutectic solvents (DESs) in the literature are the critical properties and acentric factors, which can be easily determined using the modified Lydersen–Joback–Reid (LJR) method with Lee–Kesler mixing rules. H...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099143/ https://www.ncbi.nlm.nih.gov/pubmed/37065032 http://dx.doi.org/10.1021/acsomega.3c00436 |
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author | Boublia, Abir Lemaoui, Tarek Almustafa, Ghaiath Darwish, Ahmad S. Benguerba, Yacine Banat, Fawzi AlNashef, Inas M. |
author_facet | Boublia, Abir Lemaoui, Tarek Almustafa, Ghaiath Darwish, Ahmad S. Benguerba, Yacine Banat, Fawzi AlNashef, Inas M. |
author_sort | Boublia, Abir |
collection | PubMed |
description | [Image: see text] One of the most commonly used molecular inputs for ionic liquids and deep eutectic solvents (DESs) in the literature are the critical properties and acentric factors, which can be easily determined using the modified Lydersen–Joback–Reid (LJR) method with Lee–Kesler mixing rules. However, the method used in the literature is generally applicable only to binary mixtures of DESs. Nevertheless, ternary DESs are considered to be more interesting and may provide further tailorability for developing task-specific DESs for particular applications. Therefore, in this work, a new framework for estimating the critical properties and the acentric factor of ternary DESs based on their molecular structures is presented by adjusting the framework reported in the literature with an extended version of the Lee–Kesler mixing rules. The presented framework was applied to a data set consisting of 87 ternary DESs with 334 distinct compositions. For validation, the estimated critical properties and acentric factors were used to predict the densities of the ternary DESs. The results showed excellent agreement between the experimental and calculated data, with an average absolute relative deviation (AARD) of 5.203% for ternary DESs and 5.712% for 260 binary DESs (573 compositions). The developed methodology was incorporated into a user-friendly Excel worksheet for computing the critical properties and acentric factors of any ternary or binary DES, which is provided in the Supporting Information. This work promotes the creation of robust, accessible, and user-friendly models capable of predicting the properties of new ternary DESs based on critical properties, thus saving time and resources. |
format | Online Article Text |
id | pubmed-10099143 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-100991432023-04-14 Critical Properties of Ternary Deep Eutectic Solvents Using Group Contribution with Extended Lee–Kesler Mixing Rules Boublia, Abir Lemaoui, Tarek Almustafa, Ghaiath Darwish, Ahmad S. Benguerba, Yacine Banat, Fawzi AlNashef, Inas M. ACS Omega [Image: see text] One of the most commonly used molecular inputs for ionic liquids and deep eutectic solvents (DESs) in the literature are the critical properties and acentric factors, which can be easily determined using the modified Lydersen–Joback–Reid (LJR) method with Lee–Kesler mixing rules. However, the method used in the literature is generally applicable only to binary mixtures of DESs. Nevertheless, ternary DESs are considered to be more interesting and may provide further tailorability for developing task-specific DESs for particular applications. Therefore, in this work, a new framework for estimating the critical properties and the acentric factor of ternary DESs based on their molecular structures is presented by adjusting the framework reported in the literature with an extended version of the Lee–Kesler mixing rules. The presented framework was applied to a data set consisting of 87 ternary DESs with 334 distinct compositions. For validation, the estimated critical properties and acentric factors were used to predict the densities of the ternary DESs. The results showed excellent agreement between the experimental and calculated data, with an average absolute relative deviation (AARD) of 5.203% for ternary DESs and 5.712% for 260 binary DESs (573 compositions). The developed methodology was incorporated into a user-friendly Excel worksheet for computing the critical properties and acentric factors of any ternary or binary DES, which is provided in the Supporting Information. This work promotes the creation of robust, accessible, and user-friendly models capable of predicting the properties of new ternary DESs based on critical properties, thus saving time and resources. American Chemical Society 2023-03-30 /pmc/articles/PMC10099143/ /pubmed/37065032 http://dx.doi.org/10.1021/acsomega.3c00436 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Boublia, Abir Lemaoui, Tarek Almustafa, Ghaiath Darwish, Ahmad S. Benguerba, Yacine Banat, Fawzi AlNashef, Inas M. Critical Properties of Ternary Deep Eutectic Solvents Using Group Contribution with Extended Lee–Kesler Mixing Rules |
title | Critical Properties
of Ternary Deep Eutectic Solvents
Using Group Contribution with Extended Lee–Kesler Mixing Rules |
title_full | Critical Properties
of Ternary Deep Eutectic Solvents
Using Group Contribution with Extended Lee–Kesler Mixing Rules |
title_fullStr | Critical Properties
of Ternary Deep Eutectic Solvents
Using Group Contribution with Extended Lee–Kesler Mixing Rules |
title_full_unstemmed | Critical Properties
of Ternary Deep Eutectic Solvents
Using Group Contribution with Extended Lee–Kesler Mixing Rules |
title_short | Critical Properties
of Ternary Deep Eutectic Solvents
Using Group Contribution with Extended Lee–Kesler Mixing Rules |
title_sort | critical properties
of ternary deep eutectic solvents
using group contribution with extended lee–kesler mixing rules |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099143/ https://www.ncbi.nlm.nih.gov/pubmed/37065032 http://dx.doi.org/10.1021/acsomega.3c00436 |
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