Coordination of Pnictogenylboranes Towards Tl(I) Salts and a Tl‐ Mediated P−P Coupling

The coordination chemistry of only Lewis‐base (LB)‐stabilized pnictogenylboranes EH(2)BH(2)⋅NMe( 3 ) (E=P, As) towards Tl(I) salts has been studied. The reaction of Tl[BAr(Cl)] (BAr(Cl)=[B(3,5‐C(6)H(3)Cl(2))(4)](−)) with the corresponding pnictogenylborane results in the formation of [Tl(EH(2)BH(2)⋅...

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Detalles Bibliográficos
Autores principales: Szlosek, Robert, Ackermann, Matthias T., Marquardt, Christian, Seidl, Michael, Timoshkin, Alexey Y., Scheer, Manfred
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099240/
https://www.ncbi.nlm.nih.gov/pubmed/36259382
http://dx.doi.org/10.1002/chem.202202911

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099240/
https://www.ncbi.nlm.nih.gov/pubmed/36259382
http://dx.doi.org/10.1002/chem.202202911

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