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Synthesis and Application of Alkali Metal Antimonide—A New Approach to Antimony Chemistry

Alkali metal dihydrogen‐antimonides [M(L)( x )SbH(2)], short: alkali metal antimonides (M=Li, Na, K, Rb, Cs; 1: L=pmdta; 2: L=crown‐ether), were prepared from stibine and n‐Butyllithium, M(hmds) (hmds=hexamethyldisilazane) or MOtBu, respectively. We developed a generally applicable synthesis route f...

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Detalles Bibliográficos
Autores principales: Dollberg, Kevin, Schneider, Selina, Richter, Roman‐Malte, Dunaj, Tobias, von Hänisch, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099276/
https://www.ncbi.nlm.nih.gov/pubmed/36301563
http://dx.doi.org/10.1002/anie.202213098

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