On the Mechanism of the Formal [2+2] Cycloaddition – Retro‐electrocyclization (CA‐RE) Reaction

The [2+2] cycloaddition ‐ retro‐electrocyclization (CA‐RE) reaction is a “click‐like” protocol for facile synthesis of donor‐acceptor chromophores from an alkyne and tetracyanoethylene. Herein we shed light on the mechanism of this reaction by detailed kinetics studies using (1)H NMR spectroscopy. B...

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Detalles Bibliográficos
Autores principales: Hansen, Jonathan Kirschner Solberg, Tortzen, Christian G., Sørensen, Preben Graae, Brøndsted Nielsen, Mogens
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099493/
https://www.ncbi.nlm.nih.gov/pubmed/36217899
http://dx.doi.org/10.1002/chem.202202833

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099493/
https://www.ncbi.nlm.nih.gov/pubmed/36217899
http://dx.doi.org/10.1002/chem.202202833

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