Synthesis and Catalysis of Anionic Amido Iron(II) Complexes

Low‐coordinate, open‐shell 3d metal complexes have attracted great attention due to their critical role in several catalytic transformations but have been notoriously difficult to prepare and study due to their high lability. Here, we report the synthesis of a heteroleptic tri‐coordinate amidoferrat...

Descripción completa

Detalles Bibliográficos
Autores principales: Chakraborty, Uttam, Fedulin, Andrey, Jacobi von Wangelin, Axel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099668/
https://www.ncbi.nlm.nih.gov/pubmed/37064762
http://dx.doi.org/10.1002/cctc.202201105
_version_ 1785025103574073344
author Chakraborty, Uttam
Fedulin, Andrey
Jacobi von Wangelin, Axel
author_facet Chakraborty, Uttam
Fedulin, Andrey
Jacobi von Wangelin, Axel
author_sort Chakraborty, Uttam
collection PubMed
description Low‐coordinate, open‐shell 3d metal complexes have attracted great attention due to their critical role in several catalytic transformations but have been notoriously difficult to prepare and study due to their high lability. Here, we report the synthesis of a heteroleptic tri‐coordinate amidoferrate that displays high catalytic activity in the regioselective hydrosilylation of alkenes.
format Online
Article
Text
id pubmed-10099668
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher John Wiley and Sons Inc.
record_format MEDLINE/PubMed
spelling pubmed-100996682023-04-14 Synthesis and Catalysis of Anionic Amido Iron(II) Complexes Chakraborty, Uttam Fedulin, Andrey Jacobi von Wangelin, Axel ChemCatChem Research Articles Low‐coordinate, open‐shell 3d metal complexes have attracted great attention due to their critical role in several catalytic transformations but have been notoriously difficult to prepare and study due to their high lability. Here, we report the synthesis of a heteroleptic tri‐coordinate amidoferrate that displays high catalytic activity in the regioselective hydrosilylation of alkenes. John Wiley and Sons Inc. 2022-11-24 2022-12-20 /pmc/articles/PMC10099668/ /pubmed/37064762 http://dx.doi.org/10.1002/cctc.202201105 Text en © 2022 The Authors. ChemCatChem published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc/4.0/ (https://creativecommons.org/licenses/by-nc/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Research Articles
Chakraborty, Uttam
Fedulin, Andrey
Jacobi von Wangelin, Axel
Synthesis and Catalysis of Anionic Amido Iron(II) Complexes
title Synthesis and Catalysis of Anionic Amido Iron(II) Complexes
title_full Synthesis and Catalysis of Anionic Amido Iron(II) Complexes
title_fullStr Synthesis and Catalysis of Anionic Amido Iron(II) Complexes
title_full_unstemmed Synthesis and Catalysis of Anionic Amido Iron(II) Complexes
title_short Synthesis and Catalysis of Anionic Amido Iron(II) Complexes
title_sort synthesis and catalysis of anionic amido iron(ii) complexes
topic Research Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099668/
https://www.ncbi.nlm.nih.gov/pubmed/37064762
http://dx.doi.org/10.1002/cctc.202201105
work_keys_str_mv AT chakrabortyuttam synthesisandcatalysisofanionicamidoironiicomplexes
AT fedulinandrey synthesisandcatalysisofanionicamidoironiicomplexes
AT jacobivonwangelinaxel synthesisandcatalysisofanionicamidoironiicomplexes

Ejemplares similares