Isolation and Characterization of the Homoleptic Nickel(I) and Nickel(II) Bis‐benzene Sandwich Cations

A stable salt of the metalloradical [Ni(C(6)H(6))(2)](+) hitherto unknown in the condensed phase was synthesized from [Ni(CO)(4)](+)[WCA](−) and benzene ([WCA](−)=[F{Al(OR(F))(3)}(2)](−); R(F)=C(CF(3))(3)). Single crystal XRD reveals a remarkable asymmetrically η(3),η(6)‐slipped sandwich structure....

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Detalles Bibliográficos
Autores principales: Schmitt, Manuel, Mayländer, Maximilian, Heizmann, Tim, Richert, Sabine, Bülow, Christine, Hirsch, Konstantin, Zamudio‐Bayer, Vicente, Lau, J. Tobias, Krossing, Ingo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099793/
https://www.ncbi.nlm.nih.gov/pubmed/36197000
http://dx.doi.org/10.1002/anie.202211555

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099793/
https://www.ncbi.nlm.nih.gov/pubmed/36197000
http://dx.doi.org/10.1002/anie.202211555

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