Cargando…

Advancing MXene Electrocatalysts for Energy Conversion Reactions: Surface, Stoichiometry, and Stability

MXenes, due to their tailorable chemistry and favourable physical properties, have great promise in electrocatalytic energy conversion reactions. To exploit fully their enormous potential, further advances specific to electrocatalysis revolving around their performance, stability, compositional disc...

Descripción completa

Detalles Bibliográficos
Autores principales: Tsounis, Constantine, Kumar, Priyank V., Masood, Hassan, Kulkarni, Rutvij Pankaj, Gautam, Gopalakrishnan Sai, Müller, Christoph R., Amal, Rose, Kuznetsov, Denis A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099934/
https://www.ncbi.nlm.nih.gov/pubmed/36278885
http://dx.doi.org/10.1002/anie.202210828
_version_ 1785025165531283456
author Tsounis, Constantine
Kumar, Priyank V.
Masood, Hassan
Kulkarni, Rutvij Pankaj
Gautam, Gopalakrishnan Sai
Müller, Christoph R.
Amal, Rose
Kuznetsov, Denis A.
author_facet Tsounis, Constantine
Kumar, Priyank V.
Masood, Hassan
Kulkarni, Rutvij Pankaj
Gautam, Gopalakrishnan Sai
Müller, Christoph R.
Amal, Rose
Kuznetsov, Denis A.
author_sort Tsounis, Constantine
collection PubMed
description MXenes, due to their tailorable chemistry and favourable physical properties, have great promise in electrocatalytic energy conversion reactions. To exploit fully their enormous potential, further advances specific to electrocatalysis revolving around their performance, stability, compositional discovery and synthesis are required. The most recent advances in these aspects are discussed in detail: surface functional and stoichiometric modifications which can improve performance, Pourbaix stability related to their electrocatalytic operating conditions, density functional theory and advances in machine learning for their discovery, and prospects in large scale synthesis and solution processing techniques to produce membrane electrode assemblies and integrated electrodes. This Review provides a perspective that is complemented by new density functional theory calculations which show how these recent advances in MXene material design are paving the way for effective electrocatalysts required for the transition to integrated renewable energy systems.
format Online
Article
Text
id pubmed-10099934
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher John Wiley and Sons Inc.
record_format MEDLINE/PubMed
spelling pubmed-100999342023-04-14 Advancing MXene Electrocatalysts for Energy Conversion Reactions: Surface, Stoichiometry, and Stability Tsounis, Constantine Kumar, Priyank V. Masood, Hassan Kulkarni, Rutvij Pankaj Gautam, Gopalakrishnan Sai Müller, Christoph R. Amal, Rose Kuznetsov, Denis A. Angew Chem Int Ed Engl Reviews MXenes, due to their tailorable chemistry and favourable physical properties, have great promise in electrocatalytic energy conversion reactions. To exploit fully their enormous potential, further advances specific to electrocatalysis revolving around their performance, stability, compositional discovery and synthesis are required. The most recent advances in these aspects are discussed in detail: surface functional and stoichiometric modifications which can improve performance, Pourbaix stability related to their electrocatalytic operating conditions, density functional theory and advances in machine learning for their discovery, and prospects in large scale synthesis and solution processing techniques to produce membrane electrode assemblies and integrated electrodes. This Review provides a perspective that is complemented by new density functional theory calculations which show how these recent advances in MXene material design are paving the way for effective electrocatalysts required for the transition to integrated renewable energy systems. John Wiley and Sons Inc. 2022-11-29 2023-01-23 /pmc/articles/PMC10099934/ /pubmed/36278885 http://dx.doi.org/10.1002/anie.202210828 Text en © 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ (https://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Reviews
Tsounis, Constantine
Kumar, Priyank V.
Masood, Hassan
Kulkarni, Rutvij Pankaj
Gautam, Gopalakrishnan Sai
Müller, Christoph R.
Amal, Rose
Kuznetsov, Denis A.
Advancing MXene Electrocatalysts for Energy Conversion Reactions: Surface, Stoichiometry, and Stability
title Advancing MXene Electrocatalysts for Energy Conversion Reactions: Surface, Stoichiometry, and Stability
title_full Advancing MXene Electrocatalysts for Energy Conversion Reactions: Surface, Stoichiometry, and Stability
title_fullStr Advancing MXene Electrocatalysts for Energy Conversion Reactions: Surface, Stoichiometry, and Stability
title_full_unstemmed Advancing MXene Electrocatalysts for Energy Conversion Reactions: Surface, Stoichiometry, and Stability
title_short Advancing MXene Electrocatalysts for Energy Conversion Reactions: Surface, Stoichiometry, and Stability
title_sort advancing mxene electrocatalysts for energy conversion reactions: surface, stoichiometry, and stability
topic Reviews
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10099934/
https://www.ncbi.nlm.nih.gov/pubmed/36278885
http://dx.doi.org/10.1002/anie.202210828
work_keys_str_mv AT tsounisconstantine advancingmxeneelectrocatalystsforenergyconversionreactionssurfacestoichiometryandstability
AT kumarpriyankv advancingmxeneelectrocatalystsforenergyconversionreactionssurfacestoichiometryandstability
AT masoodhassan advancingmxeneelectrocatalystsforenergyconversionreactionssurfacestoichiometryandstability
AT kulkarnirutvijpankaj advancingmxeneelectrocatalystsforenergyconversionreactionssurfacestoichiometryandstability
AT gautamgopalakrishnansai advancingmxeneelectrocatalystsforenergyconversionreactionssurfacestoichiometryandstability
AT mullerchristophr advancingmxeneelectrocatalystsforenergyconversionreactionssurfacestoichiometryandstability
AT amalrose advancingmxeneelectrocatalystsforenergyconversionreactionssurfacestoichiometryandstability
AT kuznetsovdenisa advancingmxeneelectrocatalystsforenergyconversionreactionssurfacestoichiometryandstability