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Calcium Hydride Cation Dimer Catalyzed Hydrogenation of Unactivated 1‐Alkenes and H(2) Isotope Exchange: Competitive Ca−H−Ca Bridges and Terminal Ca−H Bonds
Recently, it was shown that the double Ca−H−Ca bridged calcium hydride cation dimer complex [LCaH(2)CaL](2+) (macrocyclic ligand L=NNNN‐tetradentate Me(4)TACD) exhibited remarkable activity in catalyzing the hydrogenation of unactivated 1‐alkenes as well as the H(2) isotope exchange under mild condi...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10100058/ https://www.ncbi.nlm.nih.gov/pubmed/36214655 http://dx.doi.org/10.1002/chem.202202602 |