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Photoredox‐Mediated Deoxygenative Radical Additions of Aromatic Acids to Vinyl Boronic Esters and gem‐Diborylalkenes

A new method to access β‐keto‐gem‐diborylalkanes, by direct deoxygenative radical addition of aromatic carboxylic acids to gem‐dibortlalkenes, is described. The reaction proceeds under mild photoredox catalysis and involves the photochemical C−O bond activation of aromatic carboxylic acids in the pr...

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Detalles Bibliográficos
Autores principales: Nagaraju, Anugula, Saiaede, Tamer, Eghbarieh, Nadim, Masarwa, Ahmad
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10100356/
https://www.ncbi.nlm.nih.gov/pubmed/36222076
http://dx.doi.org/10.1002/chem.202202646