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Copper‐Catalyzed 1,2‐Dicarbonylative Cyclization of Alkenes with Alkyl Bromides via Radical Cascade Process

Herein, we developed a new procedure on 1,2‐dicarbonylative cyclization of 4‐aryl‐1‐butenes with alkyl bromides. Using simple copper catalyst, two molecules of carbon monoxide were introduced into the double bond with the formation of four new C−C bonds and a new ring. Various α‐tetralones and 2,3‐d...

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Detalles Bibliográficos
Autores principales: Zhao, Fengqian, Gu, Xing‐Wei, Franke, Robert, Wu, Xiao‐Feng
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10100518/
https://www.ncbi.nlm.nih.gov/pubmed/36254794
http://dx.doi.org/10.1002/anie.202214812