Cargando…

Layer-Structured Anisotropic Metal Chalcogenides: Recent Advances in Synthesis, Modulation, and Applications

[Image: see text] The unique electronic and catalytic properties emerging from low symmetry anisotropic (1D and 2D) metal chalcogenides (MCs) have generated tremendous interest for use in next generation electronics, optoelectronics, electrochemical energy storage devices, and chemical sensing devic...

Descripción completa

Detalles Bibliográficos
Autores principales: Giri, Anupam, Park, Gyeongbae, Jeong, Unyong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10103142/
https://www.ncbi.nlm.nih.gov/pubmed/36719999
http://dx.doi.org/10.1021/acs.chemrev.2c00455
_version_ 1785025819106607104
author Giri, Anupam
Park, Gyeongbae
Jeong, Unyong
author_facet Giri, Anupam
Park, Gyeongbae
Jeong, Unyong
author_sort Giri, Anupam
collection PubMed
description [Image: see text] The unique electronic and catalytic properties emerging from low symmetry anisotropic (1D and 2D) metal chalcogenides (MCs) have generated tremendous interest for use in next generation electronics, optoelectronics, electrochemical energy storage devices, and chemical sensing devices. Despite many proof-of-concept demonstrations so far, the full potential of anisotropic chalcogenides has yet to be investigated. This article provides a comprehensive overview of the recent progress made in the synthesis, mechanistic understanding, property modulation strategies, and applications of the anisotropic chalcogenides. It begins with an introduction to the basic crystal structures, and then the unique physical and chemical properties of 1D and 2D MCs. Controlled synthetic routes for anisotropic MC crystals are summarized with example advances in the solution-phase synthesis, vapor-phase synthesis, and exfoliation. Several important approaches to modulate dimensions, phases, compositions, defects, and heterostructures of anisotropic MCs are discussed. Recent significant advances in applications are highlighted for electronics, optoelectronic devices, catalysts, batteries, supercapacitors, sensing platforms, and thermoelectric devices. The article ends with prospects for future opportunities and challenges to be addressed in the academic research and practical engineering of anisotropic MCs.
format Online
Article
Text
id pubmed-10103142
institution National Center for Biotechnology Information
language English
publishDate 2023
publisher American Chemical Society
record_format MEDLINE/PubMed
spelling pubmed-101031422023-04-15 Layer-Structured Anisotropic Metal Chalcogenides: Recent Advances in Synthesis, Modulation, and Applications Giri, Anupam Park, Gyeongbae Jeong, Unyong Chem Rev [Image: see text] The unique electronic and catalytic properties emerging from low symmetry anisotropic (1D and 2D) metal chalcogenides (MCs) have generated tremendous interest for use in next generation electronics, optoelectronics, electrochemical energy storage devices, and chemical sensing devices. Despite many proof-of-concept demonstrations so far, the full potential of anisotropic chalcogenides has yet to be investigated. This article provides a comprehensive overview of the recent progress made in the synthesis, mechanistic understanding, property modulation strategies, and applications of the anisotropic chalcogenides. It begins with an introduction to the basic crystal structures, and then the unique physical and chemical properties of 1D and 2D MCs. Controlled synthetic routes for anisotropic MC crystals are summarized with example advances in the solution-phase synthesis, vapor-phase synthesis, and exfoliation. Several important approaches to modulate dimensions, phases, compositions, defects, and heterostructures of anisotropic MCs are discussed. Recent significant advances in applications are highlighted for electronics, optoelectronic devices, catalysts, batteries, supercapacitors, sensing platforms, and thermoelectric devices. The article ends with prospects for future opportunities and challenges to be addressed in the academic research and practical engineering of anisotropic MCs. American Chemical Society 2023-01-31 /pmc/articles/PMC10103142/ /pubmed/36719999 http://dx.doi.org/10.1021/acs.chemrev.2c00455 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Giri, Anupam
Park, Gyeongbae
Jeong, Unyong
Layer-Structured Anisotropic Metal Chalcogenides: Recent Advances in Synthesis, Modulation, and Applications
title Layer-Structured Anisotropic Metal Chalcogenides: Recent Advances in Synthesis, Modulation, and Applications
title_full Layer-Structured Anisotropic Metal Chalcogenides: Recent Advances in Synthesis, Modulation, and Applications
title_fullStr Layer-Structured Anisotropic Metal Chalcogenides: Recent Advances in Synthesis, Modulation, and Applications
title_full_unstemmed Layer-Structured Anisotropic Metal Chalcogenides: Recent Advances in Synthesis, Modulation, and Applications
title_short Layer-Structured Anisotropic Metal Chalcogenides: Recent Advances in Synthesis, Modulation, and Applications
title_sort layer-structured anisotropic metal chalcogenides: recent advances in synthesis, modulation, and applications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10103142/
https://www.ncbi.nlm.nih.gov/pubmed/36719999
http://dx.doi.org/10.1021/acs.chemrev.2c00455
work_keys_str_mv AT girianupam layerstructuredanisotropicmetalchalcogenidesrecentadvancesinsynthesismodulationandapplications
AT parkgyeongbae layerstructuredanisotropicmetalchalcogenidesrecentadvancesinsynthesismodulationandapplications
AT jeongunyong layerstructuredanisotropicmetalchalcogenidesrecentadvancesinsynthesismodulationandapplications