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Layer-Structured Anisotropic Metal Chalcogenides: Recent Advances in Synthesis, Modulation, and Applications
[Image: see text] The unique electronic and catalytic properties emerging from low symmetry anisotropic (1D and 2D) metal chalcogenides (MCs) have generated tremendous interest for use in next generation electronics, optoelectronics, electrochemical energy storage devices, and chemical sensing devic...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10103142/ https://www.ncbi.nlm.nih.gov/pubmed/36719999 http://dx.doi.org/10.1021/acs.chemrev.2c00455 |
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author | Giri, Anupam Park, Gyeongbae Jeong, Unyong |
author_facet | Giri, Anupam Park, Gyeongbae Jeong, Unyong |
author_sort | Giri, Anupam |
collection | PubMed |
description | [Image: see text] The unique electronic and catalytic properties emerging from low symmetry anisotropic (1D and 2D) metal chalcogenides (MCs) have generated tremendous interest for use in next generation electronics, optoelectronics, electrochemical energy storage devices, and chemical sensing devices. Despite many proof-of-concept demonstrations so far, the full potential of anisotropic chalcogenides has yet to be investigated. This article provides a comprehensive overview of the recent progress made in the synthesis, mechanistic understanding, property modulation strategies, and applications of the anisotropic chalcogenides. It begins with an introduction to the basic crystal structures, and then the unique physical and chemical properties of 1D and 2D MCs. Controlled synthetic routes for anisotropic MC crystals are summarized with example advances in the solution-phase synthesis, vapor-phase synthesis, and exfoliation. Several important approaches to modulate dimensions, phases, compositions, defects, and heterostructures of anisotropic MCs are discussed. Recent significant advances in applications are highlighted for electronics, optoelectronic devices, catalysts, batteries, supercapacitors, sensing platforms, and thermoelectric devices. The article ends with prospects for future opportunities and challenges to be addressed in the academic research and practical engineering of anisotropic MCs. |
format | Online Article Text |
id | pubmed-10103142 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-101031422023-04-15 Layer-Structured Anisotropic Metal Chalcogenides: Recent Advances in Synthesis, Modulation, and Applications Giri, Anupam Park, Gyeongbae Jeong, Unyong Chem Rev [Image: see text] The unique electronic and catalytic properties emerging from low symmetry anisotropic (1D and 2D) metal chalcogenides (MCs) have generated tremendous interest for use in next generation electronics, optoelectronics, electrochemical energy storage devices, and chemical sensing devices. Despite many proof-of-concept demonstrations so far, the full potential of anisotropic chalcogenides has yet to be investigated. This article provides a comprehensive overview of the recent progress made in the synthesis, mechanistic understanding, property modulation strategies, and applications of the anisotropic chalcogenides. It begins with an introduction to the basic crystal structures, and then the unique physical and chemical properties of 1D and 2D MCs. Controlled synthetic routes for anisotropic MC crystals are summarized with example advances in the solution-phase synthesis, vapor-phase synthesis, and exfoliation. Several important approaches to modulate dimensions, phases, compositions, defects, and heterostructures of anisotropic MCs are discussed. Recent significant advances in applications are highlighted for electronics, optoelectronic devices, catalysts, batteries, supercapacitors, sensing platforms, and thermoelectric devices. The article ends with prospects for future opportunities and challenges to be addressed in the academic research and practical engineering of anisotropic MCs. American Chemical Society 2023-01-31 /pmc/articles/PMC10103142/ /pubmed/36719999 http://dx.doi.org/10.1021/acs.chemrev.2c00455 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Giri, Anupam Park, Gyeongbae Jeong, Unyong Layer-Structured Anisotropic Metal Chalcogenides: Recent Advances in Synthesis, Modulation, and Applications |
title | Layer-Structured
Anisotropic Metal Chalcogenides:
Recent Advances in Synthesis, Modulation, and Applications |
title_full | Layer-Structured
Anisotropic Metal Chalcogenides:
Recent Advances in Synthesis, Modulation, and Applications |
title_fullStr | Layer-Structured
Anisotropic Metal Chalcogenides:
Recent Advances in Synthesis, Modulation, and Applications |
title_full_unstemmed | Layer-Structured
Anisotropic Metal Chalcogenides:
Recent Advances in Synthesis, Modulation, and Applications |
title_short | Layer-Structured
Anisotropic Metal Chalcogenides:
Recent Advances in Synthesis, Modulation, and Applications |
title_sort | layer-structured
anisotropic metal chalcogenides:
recent advances in synthesis, modulation, and applications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10103142/ https://www.ncbi.nlm.nih.gov/pubmed/36719999 http://dx.doi.org/10.1021/acs.chemrev.2c00455 |
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