Aromatic chloroosmacyclopentatrienes

Aromatic metallacycles are of considerable current interest. Reported aromatic metallacycles are mainly those with carbon, nitrogen, oxygen and sulfur. In this work, we report the synthesis and characterization of aromatic chloroosmacyclopentatrienes, which represent the first structurally confirmed...

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Detalles Bibliográficos
Autores principales: Chu, Zhenwei, He, Guomei, Shi, Chuan, Hua, Yuhui, Huang, Yaxi, Chen, Jiangxi, Xie, Hujun, Jia, Guochen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Oxford University Press 2022
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10103825/
https://www.ncbi.nlm.nih.gov/pubmed/37063704
http://dx.doi.org/10.1093/nsr/nwac237
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author Chu, Zhenwei
He, Guomei
Shi, Chuan
Hua, Yuhui
Huang, Yaxi
Chen, Jiangxi
Xie, Hujun
Jia, Guochen
author_facet Chu, Zhenwei
He, Guomei
Shi, Chuan
Hua, Yuhui
Huang, Yaxi
Chen, Jiangxi
Xie, Hujun
Jia, Guochen
author_sort Chu, Zhenwei
collection PubMed
description Aromatic metallacycles are of considerable current interest. Reported aromatic metallacycles are mainly those with carbon, nitrogen, oxygen and sulfur. In this work, we report the synthesis and characterization of aromatic chloroosmacyclopentatrienes, which represent the first structurally confirmed metallaaromatic with a chlorine atom in its framework. Single-crystal X-ray diffraction studies show that these planar chloroosmacyclopentatrienes possess a very short Os–ClC distance suggesting M=ClC bond character.
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spelling pubmed-101038252023-04-15 Aromatic chloroosmacyclopentatrienes Chu, Zhenwei He, Guomei Shi, Chuan Hua, Yuhui Huang, Yaxi Chen, Jiangxi Xie, Hujun Jia, Guochen Natl Sci Rev Research Article Aromatic metallacycles are of considerable current interest. Reported aromatic metallacycles are mainly those with carbon, nitrogen, oxygen and sulfur. In this work, we report the synthesis and characterization of aromatic chloroosmacyclopentatrienes, which represent the first structurally confirmed metallaaromatic with a chlorine atom in its framework. Single-crystal X-ray diffraction studies show that these planar chloroosmacyclopentatrienes possess a very short Os–ClC distance suggesting M=ClC bond character. Oxford University Press 2022-10-28 /pmc/articles/PMC10103825/ /pubmed/37063704 http://dx.doi.org/10.1093/nsr/nwac237 Text en © The Author(s) 2022. Published by Oxford University Press on behalf of China Science Publishing & Media Ltd. https://creativecommons.org/licenses/by/4.0/This is an Open Access article distributed under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Article
Chu, Zhenwei
He, Guomei
Shi, Chuan
Hua, Yuhui
Huang, Yaxi
Chen, Jiangxi
Xie, Hujun
Jia, Guochen
Aromatic chloroosmacyclopentatrienes
title Aromatic chloroosmacyclopentatrienes
title_full Aromatic chloroosmacyclopentatrienes
title_fullStr Aromatic chloroosmacyclopentatrienes
title_full_unstemmed Aromatic chloroosmacyclopentatrienes
title_short Aromatic chloroosmacyclopentatrienes
title_sort aromatic chloroosmacyclopentatrienes
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10103825/
https://www.ncbi.nlm.nih.gov/pubmed/37063704
http://dx.doi.org/10.1093/nsr/nwac237
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AT huangyaxi aromaticchloroosmacyclopentatrienes
AT chenjiangxi aromaticchloroosmacyclopentatrienes
AT xiehujun aromaticchloroosmacyclopentatrienes
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