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Polyphosphinoborane Block Copolymer Synthesis Using Catalytic Reversible Chain‐Transfer Dehydropolymerization

An amphiphilic block copolymer of polyphosphinoborane has been prepared by a mechanism‐led strategy of the sequential catalytic dehydropolymerization of precursor monomers, H(3)B ⋅ PRH(2) (R=Ph, n‐hexyl), using the simple pre‐catalyst [Rh(Ph(2)PCH(2)CH(2)PPh(2))(2)]Cl. Speciation, mechanism and poly...

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Detalles Bibliográficos
Autores principales:	Race, James J., Heyam, Alex, Wiebe, Matthew A., Diego‐Garcia Hernandez, J., Ellis, Charlotte E., Lei, Shixing, Manners, Ian, Weller, Andrew S.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107156/ https://www.ncbi.nlm.nih.gov/pubmed/36394131 http://dx.doi.org/10.1002/anie.202216106

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