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Alkaline‐Earth Metal Mediated Benzene‐to‐Biphenyl Coupling

Complex [((DIPeP)BDI)Ca](2)(C(6)H(6)), with a C(6)H(6) (2−) dianion bridging two Ca(2+) ions, reacts with benzene to yield [((DIPeP)BDI)Ca](2)(biphenyl) with a bridging biphenyl(2−) dianion ((DIPeP)BDI=HC[C(Me)N‐DIPeP](2); DIPeP=2,6‐CH(Et)(2)‐phenyl). The biphenyl complex was also prepared by reacti...

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Detalles Bibliográficos
Autores principales:	Mai, Jonathan, Morasch, Michael, Jędrzkiewicz, Dawid, Langer, Jens, Rösch, Bastian, Harder, Sjoerd
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107259/ https://www.ncbi.nlm.nih.gov/pubmed/36426597 http://dx.doi.org/10.1002/anie.202212463

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