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Synthesis and Degradation of Vinyl Polymers with Evenly Distributed Thioacetal Bonds in Main Chains: Cationic DT Copolymerization of Vinyl Ethers and Cyclic Thioacetals

We report a novel method to synthesize degradable poly(vinyl ether)s with cleavable thioacetal bonds periodically arranged in the main chains using controlled cationic copolymerization of vinyl ethers with a 7‐membered cyclic thioacetal (7‐CTA) via degenerative chain transfer (DT) to the internal th...

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Detalles Bibliográficos
Autores principales: Uchiyama, Mineto, Murakami, Yukihiro, Satoh, Kotaro, Kamigaito, Masami
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107285/
https://www.ncbi.nlm.nih.gov/pubmed/36369911
http://dx.doi.org/10.1002/anie.202215021

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