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Highly Reversible Zinc Metal Anode in a Dilute Aqueous Electrolyte Enabled by a pH Buffer Additive
Aqueous zinc‐ion batteries have drawn increasing attention due to the intrinsic safety, cost‐effectiveness and high energy density. However, parasitic reactions and non‐uniform dendrite growth on the Zn anode side impede their application. Herein, a multifunctional additive, ammonium dihydrogen phos...
Autores principales: | , , , , , , , , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107295/ https://www.ncbi.nlm.nih.gov/pubmed/36375075 http://dx.doi.org/10.1002/anie.202212695 |
Sumario: | Aqueous zinc‐ion batteries have drawn increasing attention due to the intrinsic safety, cost‐effectiveness and high energy density. However, parasitic reactions and non‐uniform dendrite growth on the Zn anode side impede their application. Herein, a multifunctional additive, ammonium dihydrogen phosphate (NHP), is introduced to regulate uniform zinc deposition and to suppress side reactions. The results show that the NH(4) (+) tends to be preferably absorbed on the Zn surface to form a “shielding effect” and blocks the direct contact of water with Zn. Moreover, NH(4) (+) and (H(2)PO(4))(−) jointly maintain pH values of the electrode‐electrolyte interface. Consequently, the NHP additive enables highly reversible Zn plating/stripping behaviors in Zn//Zn and Zn//Cu cells. Furthermore, the electrochemical performances of Zn//MnO(2) full cells and Zn//active carbon (AC) capacitors are improved. This work provides an efficient and general strategy for modifying Zn plating/stripping behaviors and suppressing side reactions in mild aqueous electrolyte. |
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