Azaarenes: 13 Rings in a Row by Cyclopentannulation

Cyclopentannulation was explored as a strategy to access large, stable azaarenes. Buchwald–Hartwig coupling of previously reported di‐ and tetrabrominated cyclopentannulated N,N′‐dihydrotetraazapentacenes furnished stable azaarenes with up to 13 six‐membered rings in a row and a length of 3.1 nm. Th...

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Detalles Bibliográficos
Autores principales: Maier, Steffen, Hippchen, Nikolai, Jester, Fabian, Dodds, Marcus, Weber, Michel, Skarjan, Leon, Rominger, Frank, Freudenberg, Jan, Bunz, Uwe H. F.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107455/
https://www.ncbi.nlm.nih.gov/pubmed/36383088
http://dx.doi.org/10.1002/anie.202214031
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author Maier, Steffen
Hippchen, Nikolai
Jester, Fabian
Dodds, Marcus
Weber, Michel
Skarjan, Leon
Rominger, Frank
Freudenberg, Jan
Bunz, Uwe H. F.
author_facet Maier, Steffen
Hippchen, Nikolai
Jester, Fabian
Dodds, Marcus
Weber, Michel
Skarjan, Leon
Rominger, Frank
Freudenberg, Jan
Bunz, Uwe H. F.
author_sort Maier, Steffen
collection PubMed
description Cyclopentannulation was explored as a strategy to access large, stable azaarenes. Buchwald–Hartwig coupling of previously reported di‐ and tetrabrominated cyclopentannulated N,N′‐dihydrotetraazapentacenes furnished stable azaarenes with up to 13 six‐membered rings in a row and a length of 3.1 nm. Their optoelectronic and semi‐conducting properties as well as their aromaticity were investigated.
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spelling pubmed-101074552023-04-18 Azaarenes: 13 Rings in a Row by Cyclopentannulation Maier, Steffen Hippchen, Nikolai Jester, Fabian Dodds, Marcus Weber, Michel Skarjan, Leon Rominger, Frank Freudenberg, Jan Bunz, Uwe H. F. Angew Chem Int Ed Engl Communications Cyclopentannulation was explored as a strategy to access large, stable azaarenes. Buchwald–Hartwig coupling of previously reported di‐ and tetrabrominated cyclopentannulated N,N′‐dihydrotetraazapentacenes furnished stable azaarenes with up to 13 six‐membered rings in a row and a length of 3.1 nm. Their optoelectronic and semi‐conducting properties as well as their aromaticity were investigated. John Wiley and Sons Inc. 2022-12-22 2023-01-26 /pmc/articles/PMC10107455/ /pubmed/36383088 http://dx.doi.org/10.1002/anie.202214031 Text en © 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Communications
Maier, Steffen
Hippchen, Nikolai
Jester, Fabian
Dodds, Marcus
Weber, Michel
Skarjan, Leon
Rominger, Frank
Freudenberg, Jan
Bunz, Uwe H. F.
Azaarenes: 13 Rings in a Row by Cyclopentannulation
title Azaarenes: 13 Rings in a Row by Cyclopentannulation
title_full Azaarenes: 13 Rings in a Row by Cyclopentannulation
title_fullStr Azaarenes: 13 Rings in a Row by Cyclopentannulation
title_full_unstemmed Azaarenes: 13 Rings in a Row by Cyclopentannulation
title_short Azaarenes: 13 Rings in a Row by Cyclopentannulation
title_sort azaarenes: 13 rings in a row by cyclopentannulation
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107455/
https://www.ncbi.nlm.nih.gov/pubmed/36383088
http://dx.doi.org/10.1002/anie.202214031
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