Differences in the Reactivity of Geminal Si−O−P and Al−O−P Frustrated Lewis Pairs

The new oxygen‐bridged geminal Si/P Frustrated Lewis Pair (FLP) tBu(2)P−O−Si(C(2)F(5))(3) (2) is able to reversibly bind carbon dioxide at ambient temperature. We compared its reactivity towards benzil, but‐3‐en‐2‐one, nitriles and phenylacetylene to that of the Al/P FLP tBu(2)P−O−AlBis(2) (Bis=−CH(...

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Detalles Bibliográficos
Autores principales: Wickemeyer, Lucas, Hartmann, Lukas, Neumann, Beate, Stammler, Hans‐Georg, Mitzel, Norbert W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107522/
https://www.ncbi.nlm.nih.gov/pubmed/36349870
http://dx.doi.org/10.1002/chem.202202842

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107522/
https://www.ncbi.nlm.nih.gov/pubmed/36349870
http://dx.doi.org/10.1002/chem.202202842

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