Crystalline Anions Based on Classical N‐Heterocyclic Carbenes

Herein, the first stable anions K[SIPr(Bp)] (4 a‐K) and K[IPr(Bp)] (4 b‐K) (SIPr(Bp)=BpC{N(Dipp)CH(2)}(2), IPr(Bp)=BpC{N(Dipp)CH}(2); Bp=4‐PhC(6)H(4); Dipp=2,6‐iPr(2)C(6)H(3)) derived from classical N‐heterocyclic carbenes (NHCs) (i.e. SIPr and IPr) have been isolated as violet crystalline solids. 4...

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Detalles Bibliográficos
Autores principales: Merschel, Arne, Rottschäfer, Dennis, Neumann, Beate, Stammler, Hans‐Georg, Ringenberg, Mark, van Gastel, Maurice, Demirer, T. Ilgin, Andrada, Diego M., Ghadwal, Rajendra S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107637/
https://www.ncbi.nlm.nih.gov/pubmed/36398890
http://dx.doi.org/10.1002/anie.202215244

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107637/
https://www.ncbi.nlm.nih.gov/pubmed/36398890
http://dx.doi.org/10.1002/anie.202215244

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