Cargando…

Crystalline Anions Based on Classical N‐Heterocyclic Carbenes

Herein, the first stable anions K[SIPr(Bp)] (4 a‐K) and K[IPr(Bp)] (4 b‐K) (SIPr(Bp)=BpC{N(Dipp)CH(2)}(2), IPr(Bp)=BpC{N(Dipp)CH}(2); Bp=4‐PhC(6)H(4); Dipp=2,6‐iPr(2)C(6)H(3)) derived from classical N‐heterocyclic carbenes (NHCs) (i.e. SIPr and IPr) have been isolated as violet crystalline solids. 4...

Descripción completa

Detalles Bibliográficos
Autores principales:	Merschel, Arne, Rottschäfer, Dennis, Neumann, Beate, Stammler, Hans‐Georg, Ringenberg, Mark, van Gastel, Maurice, Demirer, T. Ilgin, Andrada, Diego M., Ghadwal, Rajendra S.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107637/ https://www.ncbi.nlm.nih.gov/pubmed/36398890 http://dx.doi.org/10.1002/anie.202215244

Ejemplares similares

Kekulé diradicaloids derived from a classical N-heterocyclic carbene
por: Rottschäfer, Dennis, et al.
Publicado: (2018)

Direct functionalization of white phosphorus with anionic dicarbenes and mesoionic carbenes: facile access to 1,2,3-triphosphol-2-ides
por: Rottschäfer, Dennis, et al.
Publicado: (2019)

Nickel‐Catalyzed Intramolecular 1,2‐Aryl Migration of Mesoionic Carbenes (iMICs)
por: Merschel, Arne, et al.
Publicado: (2020)

Crystalline Divinyldiarsene Radical Cations and Dications
por: Sharma, Mahendra K., et al.
Publicado: (2019)

Metalloradical Cations and Dications Based on Divinyldiphosphene and Divinyldiarsene Ligands
por: Sharma, Mahendra K., et al.
Publicado: (2021)

Isolation of singlet carbene derived 2-phospha-1,3-butadienes and their sequential one-electron oxidation to radical cations and dications
por: Sharma, Mahendra K., et al.
Publicado: (2020)

Isolation of a 16π‐Electrons 1,4‐Diphosphinine‐1,4‐diide with a Planar C(4)P(2) Ring
por: Rottschäfer, Dennis, et al.
Publicado: (2021)

Isolation of 1,4‐Diarsinine‐1,4‐diide and 1,4‐Diarsinine Derivatives
por: Rottschäfer, Dennis, et al.
Publicado: (2021)

An Open‐Shell Singlet Sn(I) Diradical and H(2) Splitting
por: Sharma, Mahendra K., et al.
Publicado: (2021)

Mesoionic Dithiolates (MIDts) Derived from 1,3‐Imidazole‐Based Anionic Dicarbenes (ADCs)
por: Ebeler, Falk, et al.
Publicado: (2022)

Halogen Complexes of Anionic N‐Heterocyclic Carbenes
por: Frosch, Jenni, et al.
Publicado: (2020)

Isolation of an Arsenic Diradicaloid with a Cyclic C(2)As(2)‐Core
por: Steffenfauseweh, Henric, et al.
Publicado: (2022)

N‐Heterocyclic Carbenes Carrying Weakly Coordinating Anions
por: Ho, Luong Phong, et al.
Publicado: (2022)

N‐Heterocyclic Carbene Acyl Anion Organocatalysis by Ball‐Milling
por: Nicholson, William I., et al.
Publicado: (2019)

Distannabarrelenes with Three Coordinated Sn(II) Atoms
por: Sharma, Mahendra K., et al.
Publicado: (2020)

Group 13 Element Trihalide Complexes of Anionic N‐Heterocyclic Carbenes
por: Ho, Luong Phong, et al.
Publicado: (2020)

Direct estimate of the internal π-donation to the carbene centre within N-heterocyclic carbenes and related molecules
por: Andrada, Diego M, et al.
Publicado: (2015)

Heterobimetallic Coinage Metal‐Ruthenium Complexes Supported by Anionic N‐Heterocyclic Carbenes
por: Planer, Sebastian, et al.
Publicado: (2021)

Rhodium and Iridium Complexes of Anionic Thione and Selone Ligands Derived from Anionic N‐Heterocyclic Carbenes
por: Ho, Luong Phong, et al.
Publicado: (2021)

N-Heterocyclic carbenes
por: Nolan, Steven P
Publicado: (2015)

N‐Heterocyclic Carbene Organocatalysis: With or Without Carbenes?
por: Gehrke, Sascha, et al.
Publicado: (2020)

Sulfur, mercury, and boron adducts of sydnone imine derived anionic N-heterocyclic carbenes
por: Freese, Tyll, et al.
Publicado: (2019)

Tricyanoborane‐Functionalized Anionic N‐Heterocyclic Carbenes: Adjustment of Charge and Stereo‐Electronic Properties
por: Zapf, Ludwig, et al.
Publicado: (2022)

From betaines to anionic N-heterocyclic carbenes. Borane, gold, rhodium, and nickel complexes starting from an imidazoliumphenolate and its carbene tautomer
por: Liu, Ming, et al.
Publicado: (2016)

Mercury(II) Complexes of Anionic N-Heterocyclic Carbene Ligands: Steric Effects of the Backbone Substituent
por: Dash, Chandrakanta, et al.
Publicado: (2020)

Sydnone Methides—A Forgotten Class of Mesoionic Compounds for the Generation of Anionic N‐Heterocyclic Carbenes
por: Mummel, Sebastian, et al.
Publicado: (2021)

Non‐Coordinated Phenolate Anions and Their Application in SF(6) Activation
por: Weitkamp, Robin F., et al.
Publicado: (2020)

Synthesis and Reactivity of the First Isolated Hydrogen‐Bridged Silanol–Silanolate Anions
por: Weitkamp, Robin F., et al.
Publicado: (2020)

Non‐coordinated and Hydrogen Bonded Phenolate Anions as One‐Electron Reducing Agents
por: Weitkamp, Robin F., et al.
Publicado: (2021)

Oxidative N‐Heterocyclic Carbene Catalysis
por: De Risi, Carmela, et al.
Publicado: (2022)

The Influence of Weakly Coordinating Cations on the O−H⋅⋅⋅O(−) Hydrogen Bond of Silanol‐Silanolate Anions
por: Weitkamp, Robin F., et al.
Publicado: (2020)

Generation and Applications of the Hydroxide Trihydrate Anion, [OH(OH(2))(3)](−), Stabilized by a Weakly Coordinating Cation
por: Weitkamp, Robin F., et al.
Publicado: (2019)

Actinide tetra-N-heterocyclic carbene ‘sandwiches’
por: DeJesus, Joseph F., et al.
Publicado: (2021)

N-Heterocyclic carbene-based gold etchants
por: Chevalier, Robert B, et al.
Publicado: (2023)

Oxidative Additions of C−F Bonds to the Silanide Anion [Si(C(2)F(5))(3)](−)
por: Tiessen, Natalia, et al.
Publicado: (2022)

Exploring Au(i) involving halogen bonding with N-heterocyclic carbene Au(i) aryl complexes in crystalline media
por: Mikherdov, Alexander S., et al.
Publicado: (2023)

Synthesis and structural studies of N-heterocyclic carbene Ag(I) and Hg(II) complexes and recognition of dihydrogen phosphate anion
por: Liu, Qingxiang, et al.
Publicado: (2017)

1,3‐Bis(tricyanoborane)imidazoline‐2‐ylidenate Anion—A Ditopic Dianionic N‐Heterocyclic Carbene Ligand
por: Zapf, Ludwig, et al.
Publicado: (2021)

Alkyne hydroarylation with Au N-heterocyclic carbene catalysts
por: Tubaro, Cristina, et al.
Publicado: (2013)

Self-Supported N-Heterocyclic Carbenes and Their Use as Organocatalysts
por: Ma, Shuang, et al.
Publicado: (2016)

Cannot write session to /tmp/vufind_sessions/sess_f900p8p94k8drmbq1dtfp8ttq1