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Energy Transport in Dichroic Metallo‐organic Crystals: Selective Inclusion of Spatially Resolved Arrays of Donor and Acceptor Dyes in Different Nanochannels
In this study, the precise positioning and alignment of arrays of two different guest molecules in a crystalline host matrix has been engineered and resulted in new optically active materials. Sub‐nm differences in the diameters of two types of 1D channels are sufficient for size‐selective inclusion...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107947/ https://www.ncbi.nlm.nih.gov/pubmed/36385565 http://dx.doi.org/10.1002/anie.202214041 |
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author | Wen, Qiang Malik, Naveen Addadi, Yoseph Weißenfels, Maren Singh, Vivek Shimon, Linda J. W. Lahav, Michal van der Boom, Milko E. |
author_facet | Wen, Qiang Malik, Naveen Addadi, Yoseph Weißenfels, Maren Singh, Vivek Shimon, Linda J. W. Lahav, Michal van der Boom, Milko E. |
author_sort | Wen, Qiang |
collection | PubMed |
description | In this study, the precise positioning and alignment of arrays of two different guest molecules in a crystalline host matrix has been engineered and resulted in new optically active materials. Sub‐nm differences in the diameters of two types of 1D channels are sufficient for size‐selective inclusion of dyes. Energy transport occurs between the arrays of different dyes that are included in parallel‐positioned nanochannels by Förster resonance energy transfer (FRET). The color of individual micro‐sized crystals are dependent on their relative position under polarized light. This angular‐dependent behavior is a result of the geometrically constrained orientation of the dyes by the crystallographic packing of the host matrix and is concentration dependent. |
format | Online Article Text |
id | pubmed-10107947 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-101079472023-04-18 Energy Transport in Dichroic Metallo‐organic Crystals: Selective Inclusion of Spatially Resolved Arrays of Donor and Acceptor Dyes in Different Nanochannels Wen, Qiang Malik, Naveen Addadi, Yoseph Weißenfels, Maren Singh, Vivek Shimon, Linda J. W. Lahav, Michal van der Boom, Milko E. Angew Chem Int Ed Engl Research Articles In this study, the precise positioning and alignment of arrays of two different guest molecules in a crystalline host matrix has been engineered and resulted in new optically active materials. Sub‐nm differences in the diameters of two types of 1D channels are sufficient for size‐selective inclusion of dyes. Energy transport occurs between the arrays of different dyes that are included in parallel‐positioned nanochannels by Förster resonance energy transfer (FRET). The color of individual micro‐sized crystals are dependent on their relative position under polarized light. This angular‐dependent behavior is a result of the geometrically constrained orientation of the dyes by the crystallographic packing of the host matrix and is concentration dependent. John Wiley and Sons Inc. 2022-12-16 2023-01-23 /pmc/articles/PMC10107947/ /pubmed/36385565 http://dx.doi.org/10.1002/anie.202214041 Text en © 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited. |
spellingShingle | Research Articles Wen, Qiang Malik, Naveen Addadi, Yoseph Weißenfels, Maren Singh, Vivek Shimon, Linda J. W. Lahav, Michal van der Boom, Milko E. Energy Transport in Dichroic Metallo‐organic Crystals: Selective Inclusion of Spatially Resolved Arrays of Donor and Acceptor Dyes in Different Nanochannels |
title | Energy Transport in Dichroic Metallo‐organic Crystals: Selective Inclusion of Spatially Resolved Arrays of Donor and Acceptor Dyes in Different Nanochannels
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title_full | Energy Transport in Dichroic Metallo‐organic Crystals: Selective Inclusion of Spatially Resolved Arrays of Donor and Acceptor Dyes in Different Nanochannels
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title_fullStr | Energy Transport in Dichroic Metallo‐organic Crystals: Selective Inclusion of Spatially Resolved Arrays of Donor and Acceptor Dyes in Different Nanochannels
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title_full_unstemmed | Energy Transport in Dichroic Metallo‐organic Crystals: Selective Inclusion of Spatially Resolved Arrays of Donor and Acceptor Dyes in Different Nanochannels
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title_short | Energy Transport in Dichroic Metallo‐organic Crystals: Selective Inclusion of Spatially Resolved Arrays of Donor and Acceptor Dyes in Different Nanochannels
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title_sort | energy transport in dichroic metallo‐organic crystals: selective inclusion of spatially resolved arrays of donor and acceptor dyes in different nanochannels |
topic | Research Articles |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107947/ https://www.ncbi.nlm.nih.gov/pubmed/36385565 http://dx.doi.org/10.1002/anie.202214041 |
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