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A Novel Electrode for Value‐Generating Anode Reactions in Water Electrolyzers at Industrial Current Densities

Hydrogen generated in electrolyzers is discussed as a key element in future energy scenarios, but oxygen evolution as the standard anode reaction is a complex multi‐step reaction requiring a high overpotential. At the same time,it does not add value‐the oxygen is typically released into the atmosphe...

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Detalles Bibliográficos
Autores principales: Wang, Changlong, Wu, Yufeng, Bodach, Alexander, Krebs, Moritz Lukas, Schuhmann, Wolfgang, Schüth, Ferdi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107951/
https://www.ncbi.nlm.nih.gov/pubmed/36440966
http://dx.doi.org/10.1002/anie.202215804
Descripción
Sumario:Hydrogen generated in electrolyzers is discussed as a key element in future energy scenarios, but oxygen evolution as the standard anode reaction is a complex multi‐step reaction requiring a high overpotential. At the same time,it does not add value‐the oxygen is typically released into the atmosphere. Alternative anode reactions which can proceed at similar current densities as the hydrogen evolution are, therefore, of highest interest. We have discovered a high‐performance electrode based on earth‐abundant elements synthesized in the presence of H(2)O(2), which is able to sustain current densities of close to 1 A cm(−2) for the oxidation of many organic molecules, which are partly needed at high production volumes. Such anode reactions could generate additional revenue streams, which help to solve one of the most important problems in the transition to renewable energy systems, i.e. the cost of hydrogen electrolysis.