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A Novel Electrode for Value‐Generating Anode Reactions in Water Electrolyzers at Industrial Current Densities

Hydrogen generated in electrolyzers is discussed as a key element in future energy scenarios, but oxygen evolution as the standard anode reaction is a complex multi‐step reaction requiring a high overpotential. At the same time,it does not add value‐the oxygen is typically released into the atmosphe...

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Autores principales: Wang, Changlong, Wu, Yufeng, Bodach, Alexander, Krebs, Moritz Lukas, Schuhmann, Wolfgang, Schüth, Ferdi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107951/
https://www.ncbi.nlm.nih.gov/pubmed/36440966
http://dx.doi.org/10.1002/anie.202215804
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author Wang, Changlong
Wu, Yufeng
Bodach, Alexander
Krebs, Moritz Lukas
Schuhmann, Wolfgang
Schüth, Ferdi
author_facet Wang, Changlong
Wu, Yufeng
Bodach, Alexander
Krebs, Moritz Lukas
Schuhmann, Wolfgang
Schüth, Ferdi
author_sort Wang, Changlong
collection PubMed
description Hydrogen generated in electrolyzers is discussed as a key element in future energy scenarios, but oxygen evolution as the standard anode reaction is a complex multi‐step reaction requiring a high overpotential. At the same time,it does not add value‐the oxygen is typically released into the atmosphere. Alternative anode reactions which can proceed at similar current densities as the hydrogen evolution are, therefore, of highest interest. We have discovered a high‐performance electrode based on earth‐abundant elements synthesized in the presence of H(2)O(2), which is able to sustain current densities of close to 1 A cm(−2) for the oxidation of many organic molecules, which are partly needed at high production volumes. Such anode reactions could generate additional revenue streams, which help to solve one of the most important problems in the transition to renewable energy systems, i.e. the cost of hydrogen electrolysis.
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spelling pubmed-101079512023-04-18 A Novel Electrode for Value‐Generating Anode Reactions in Water Electrolyzers at Industrial Current Densities Wang, Changlong Wu, Yufeng Bodach, Alexander Krebs, Moritz Lukas Schuhmann, Wolfgang Schüth, Ferdi Angew Chem Int Ed Engl Communications Hydrogen generated in electrolyzers is discussed as a key element in future energy scenarios, but oxygen evolution as the standard anode reaction is a complex multi‐step reaction requiring a high overpotential. At the same time,it does not add value‐the oxygen is typically released into the atmosphere. Alternative anode reactions which can proceed at similar current densities as the hydrogen evolution are, therefore, of highest interest. We have discovered a high‐performance electrode based on earth‐abundant elements synthesized in the presence of H(2)O(2), which is able to sustain current densities of close to 1 A cm(−2) for the oxidation of many organic molecules, which are partly needed at high production volumes. Such anode reactions could generate additional revenue streams, which help to solve one of the most important problems in the transition to renewable energy systems, i.e. the cost of hydrogen electrolysis. John Wiley and Sons Inc. 2022-12-16 2023-02-06 /pmc/articles/PMC10107951/ /pubmed/36440966 http://dx.doi.org/10.1002/anie.202215804 Text en © 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ (https://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Communications
Wang, Changlong
Wu, Yufeng
Bodach, Alexander
Krebs, Moritz Lukas
Schuhmann, Wolfgang
Schüth, Ferdi
A Novel Electrode for Value‐Generating Anode Reactions in Water Electrolyzers at Industrial Current Densities
title A Novel Electrode for Value‐Generating Anode Reactions in Water Electrolyzers at Industrial Current Densities
title_full A Novel Electrode for Value‐Generating Anode Reactions in Water Electrolyzers at Industrial Current Densities
title_fullStr A Novel Electrode for Value‐Generating Anode Reactions in Water Electrolyzers at Industrial Current Densities
title_full_unstemmed A Novel Electrode for Value‐Generating Anode Reactions in Water Electrolyzers at Industrial Current Densities
title_short A Novel Electrode for Value‐Generating Anode Reactions in Water Electrolyzers at Industrial Current Densities
title_sort novel electrode for value‐generating anode reactions in water electrolyzers at industrial current densities
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107951/
https://www.ncbi.nlm.nih.gov/pubmed/36440966
http://dx.doi.org/10.1002/anie.202215804
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