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A Novel Electrode for Value‐Generating Anode Reactions in Water Electrolyzers at Industrial Current Densities
Hydrogen generated in electrolyzers is discussed as a key element in future energy scenarios, but oxygen evolution as the standard anode reaction is a complex multi‐step reaction requiring a high overpotential. At the same time,it does not add value‐the oxygen is typically released into the atmosphe...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107951/ https://www.ncbi.nlm.nih.gov/pubmed/36440966 http://dx.doi.org/10.1002/anie.202215804 |
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author | Wang, Changlong Wu, Yufeng Bodach, Alexander Krebs, Moritz Lukas Schuhmann, Wolfgang Schüth, Ferdi |
author_facet | Wang, Changlong Wu, Yufeng Bodach, Alexander Krebs, Moritz Lukas Schuhmann, Wolfgang Schüth, Ferdi |
author_sort | Wang, Changlong |
collection | PubMed |
description | Hydrogen generated in electrolyzers is discussed as a key element in future energy scenarios, but oxygen evolution as the standard anode reaction is a complex multi‐step reaction requiring a high overpotential. At the same time,it does not add value‐the oxygen is typically released into the atmosphere. Alternative anode reactions which can proceed at similar current densities as the hydrogen evolution are, therefore, of highest interest. We have discovered a high‐performance electrode based on earth‐abundant elements synthesized in the presence of H(2)O(2), which is able to sustain current densities of close to 1 A cm(−2) for the oxidation of many organic molecules, which are partly needed at high production volumes. Such anode reactions could generate additional revenue streams, which help to solve one of the most important problems in the transition to renewable energy systems, i.e. the cost of hydrogen electrolysis. |
format | Online Article Text |
id | pubmed-10107951 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2022 |
publisher | John Wiley and Sons Inc. |
record_format | MEDLINE/PubMed |
spelling | pubmed-101079512023-04-18 A Novel Electrode for Value‐Generating Anode Reactions in Water Electrolyzers at Industrial Current Densities Wang, Changlong Wu, Yufeng Bodach, Alexander Krebs, Moritz Lukas Schuhmann, Wolfgang Schüth, Ferdi Angew Chem Int Ed Engl Communications Hydrogen generated in electrolyzers is discussed as a key element in future energy scenarios, but oxygen evolution as the standard anode reaction is a complex multi‐step reaction requiring a high overpotential. At the same time,it does not add value‐the oxygen is typically released into the atmosphere. Alternative anode reactions which can proceed at similar current densities as the hydrogen evolution are, therefore, of highest interest. We have discovered a high‐performance electrode based on earth‐abundant elements synthesized in the presence of H(2)O(2), which is able to sustain current densities of close to 1 A cm(−2) for the oxidation of many organic molecules, which are partly needed at high production volumes. Such anode reactions could generate additional revenue streams, which help to solve one of the most important problems in the transition to renewable energy systems, i.e. the cost of hydrogen electrolysis. John Wiley and Sons Inc. 2022-12-16 2023-02-06 /pmc/articles/PMC10107951/ /pubmed/36440966 http://dx.doi.org/10.1002/anie.202215804 Text en © 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ (https://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made. |
spellingShingle | Communications Wang, Changlong Wu, Yufeng Bodach, Alexander Krebs, Moritz Lukas Schuhmann, Wolfgang Schüth, Ferdi A Novel Electrode for Value‐Generating Anode Reactions in Water Electrolyzers at Industrial Current Densities |
title | A Novel Electrode for Value‐Generating Anode Reactions in Water Electrolyzers at Industrial Current Densities |
title_full | A Novel Electrode for Value‐Generating Anode Reactions in Water Electrolyzers at Industrial Current Densities |
title_fullStr | A Novel Electrode for Value‐Generating Anode Reactions in Water Electrolyzers at Industrial Current Densities |
title_full_unstemmed | A Novel Electrode for Value‐Generating Anode Reactions in Water Electrolyzers at Industrial Current Densities |
title_short | A Novel Electrode for Value‐Generating Anode Reactions in Water Electrolyzers at Industrial Current Densities |
title_sort | novel electrode for value‐generating anode reactions in water electrolyzers at industrial current densities |
topic | Communications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10107951/ https://www.ncbi.nlm.nih.gov/pubmed/36440966 http://dx.doi.org/10.1002/anie.202215804 |
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